Interplay of solvent motion and vibrational excitation in electron-transfer kinetics : experiment and theory

摘要: This paper reports new kinetic data on the electron-transfer kinetics of betaine-30 and related compound tert-butylbetaine. The experimental are in excellent agreement with a theoretical model which is an extension approach given by Sumi Marcus (Sumi, H; Marcus, R. A. J. Chem. Phys. 1986, 84, 4894). Most parameters required for predictions can be obtained straightforward fashion fitting static absorption spectra charge-transfer band