INCLUSION COMPOUNDS OF NAI WITH 13-MEMBERED AZO- AND AZOXYCROWN ETHERS
作者： Yu. A. SIMONOV , E. LUBOCH , J. F. BIERNAT , N. V. BOLOTINA , V. E. ZAVODNIK
关键词: Stereochemistry 、 Crystal structure 、 Azoxy 、 Medicinal chemistry 、 Triclinic crystal system 、 Orthorhombic crystal system 、 X ray analysis 、 Oxygen atom 、 Nitrogen atom 、 Chemistry 、 Sodium iodide
摘要: Sodium iodide complexes of 13-membered azo-(I)and azoxycrown ethers (II) have been synthesized. Compound I[Na(L1 trans)2]⋅I⋅H2O is triclinic witha = 11.53(2), b 15.74(2), c 19.17(2) A,α 98.93(9), β 105.51(9),γ 89.20(9) deg.; Z 4, space groupP1. II [Na(L2)2]⋅I orthorhombic 12.451(2), 13.796(3), 18.667(4)A; group P212121. In bothcomplexes the cation coordinated tochain oxygen atoms and to one nitrogen atom azoor azoxy unit. The ability bothligands form in relation thegeometry azo or subunit themacrocycle discussed.
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