An efficient green synthesis of quinoxaline derivatives using carbon-doped MoO3–TiO2 as a heterogeneous catalyst

作者: Machhindra Lande , Madhukar Navgire , Sandip Rathod , Santosh Katkar , Ajeet Yelwande

DOI: 10.1016/J.JIEC.2011.11.048

关键词: CatalysisEnergy-dispersive X-ray spectroscopyMaterials scienceBenzilScanning electron microscopeQuinoxalineCarbonOrganic chemistryNuclear chemistryFourier transform infrared spectroscopyHeterogeneous catalysis

摘要: Abstract A series of carbon-doped MoO3–TiO2 (CMT) material were prepared by sol–gel method. The catalyst has been characterized means X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared (FT-IR). natural wood plant Acacia arabica used as a source for carbon substrate. effect variation wt.% doping was successfully evaluated the preparation quinoxalines condensation benzil 1,2-diamine under ultra-sonication in EtOH:water (3:1). merits present investigation are extremely short reaction times, mild conditions, excellent yield, simple workup environmentally benign process.

参考文章(35)
S.K Maity, M.S Rana, B.N Srinivas, S.K Bej, G Murali Dhar, T.S.R Prasada Rao, Characterization and evaluation of ZrO2 supported hydrotreating catalysts Journal of Molecular Catalysis A-chemical. ,vol. 153, pp. 121- 127 ,(2000) , 10.1016/S1381-1169(99)00311-8
Jacques Livage, Marc Henry, Clément Sanchez, Sol-gel chemistry of transition metal oxides Progress in Solid State Chemistry. ,vol. 18, pp. 259- 341 ,(1988) , 10.1016/0079-6786(88)90005-2
Stuart Dailey, W. James Feast, Richard J. Peace, Ian C. Sage, Stephen Till, Emma L. Wood, Synthesis and device characterisation of side-chain polymer electron transport materials for organic semiconductor applications Journal of Materials Chemistry. ,vol. 11, pp. 2238- 2243 ,(2001) , 10.1039/B104674H
Muneyoshi Yamada, Junichi Yasumaru, Marwan Houalla, David M. Hercules, Distribution of molybdenum oxidation states in reduced molybdenum/alumina catalysts: correlation with benzene hydrogenation activity The Journal of Physical Chemistry. ,vol. 94, pp. 1520- 1526 ,(1990) , 10.1021/J100171A058
Haiyan Luo, Mingdeng Wei, Kemei Wei, A new metastable phase of crystallized MoO3·0.3H2O nanobelts Materials Chemistry and Physics. ,vol. 113, pp. 85- 90 ,(2009) , 10.1016/J.MATCHEMPHYS.2008.07.059
Yoshihito. Matsuoka, Miki. Niwa, Yuichi. Murakami, Morphology of molybdena supported on various oxides and its activity for methanol oxidation The Journal of Physical Chemistry. ,vol. 94, pp. 1477- 1482 ,(1990) , 10.1021/J100367A051
M.V Landau, L Vradman, M Herskowitz, Y Koltypin, A Gedanken, Ultrasonically controlled deposition-precipitation: Co-Mo HDS catalysts deposited on wide-pore MCM material Journal of Catalysis. ,vol. 201, pp. 22- 36 ,(2001) , 10.1006/JCAT.2001.3227
Won-Ju Shin, Je-Yun Lee, Jae Chang Kim, Tae-Hoon Yoon, Tae-Shick Kim, Ok-Keun Song, Bulk and interface properties of molybdenum trioxide-doped hole transporting layer in organic light-emitting diodes Organic Electronics. ,vol. 9, pp. 333- 338 ,(2008) , 10.1016/J.ORGEL.2007.12.001