Activated carbon adsorption of gold from cyanide-starved glycine solutions containing copper. Part 1: Isotherms

作者: P.J. Tauetsile , E.A. Oraby , J.J. Eksteen

DOI: 10.1016/J.SEPPUR.2018.09.022

关键词: Inorganic chemistryAdsorptionAqueous solutionFreundlich equationActivated carbonChemistryCarbonCyanideReagentCopper

摘要: Abstract Cyanide-starved alkaline glycine solutions have been shown to distinct advantages in terms of lower reagent consumption and detoxification needs, or leach rate recovery, over cyanide- only glycine-only systems respectively for gold ores with nuisance copper. Activated carbon has be suitable adsorption from systems, is well established cyanide based systems. being an effective substrate the thus offers a possible downstream carbon-in-pulp (CIP) recovery route hybrid presence cyanide. Given frequent occurrence deposits high levels copper, equilibrium loading copper onto activated cyanide-starved containing studied. Adsorption efficiency was studied isotherms. Results showed that while more sporadic on goodness fit, consistent clearly follows Freundlich isotherm model (good linear correlation log Q vs C values). The isotherms were obtained using concentration 2 ppm. In increases increasing calcium ion concentrations, decreases not affected by initial concentration. cuprous cupric glycinate complexes lowered through competitive (I) adsorbing rapidly than their counterparts. capacity 2 ppm Au 300 ppm Cu, at pH 11 found 9.95 kgAu/toncarbon 24 h, which almost four times higher pure system (2.7 kgAu/toncarbon) under similar conditions. study revealed adsorbent removal cyanide-glycine aqueous solutions.

参考文章(57)
Iain House, John Marsden, The chemistry of gold extraction ,(1969)
H.P. Boehm, Chemical Identification of Surface Groups Advances in Catalysis. ,vol. 16, pp. 179- 274 ,(1966) , 10.1016/S0360-0564(08)60354-5
Stephen J. Randtke, Christopher P. Jepsen, Effects of salts on activated carbon adsorption of fulvic acids Journal - American Water Works Association. ,vol. 74, pp. 84- 93 ,(1982) , 10.1002/J.1551-8833.1982.TB04854.X
Stephen J. Randtke, Christopher P. Jepsen, Chemical pretreatment for activated-carbon adsorption Journal - American Water Works Association. ,vol. 73, pp. 411- 419 ,(1981) , 10.1002/J.1551-8833.1981.TB04751.X
Michael C. Lee, Vernon L. Snoeyink, John C. Crittenden, Activated carbon adsorption of humic substances Journal - American Water Works Association. ,vol. 73, pp. 440- 446 ,(1981) , 10.1002/J.1551-8833.1981.TB04755.X
ANTHONY W. BRYSON, Gold Adsorption by Activated Carbon and Resin Mineral Processing and Extractive Metallurgy Review. ,vol. 15, pp. 145- 151 ,(1995) , 10.1080/08827509508914192
Ali Behnamfard, Mohammad Mehdi Salarirad, Equilibrium and kinetic studies on free cyanide adsorption from aqueous solution by activated carbon Journal of Hazardous Materials. ,vol. 170, pp. 127- 133 ,(2009) , 10.1016/J.JHAZMAT.2009.04.124
Stuart A. Manktelow, John G. Paterson, John A. Meech, Removal of copper and cyanide from solution using activated carbon Minerals and the Environment. ,vol. 6, pp. 5- 9 ,(1984) , 10.1007/BF02072660