Removal of Cu(II) from Water by a Novel Graphene Oxide/Hexadecyltrimethylammonium Composite Sponge and Its Regeneration for Reuse

作者: Baohua Song , Donglei Zou , Yongsheng Zhao , Yue Kuang , Zhenhua Sun

DOI: 10.1007/S11270-020-04665-0

关键词: DesorptionAdsorptionChemistryGrapheneOxideWater treatmentFiltrationReagentChemical engineeringSpecific surface area

摘要: Graphene oxide has great potential for use as an adsorbent due to the high specific surface area, negative charges, and abundant oxygen-containing functional groups. However, difficulty of graphene separate from water renders it impractical real treatment. In present study, a novel oxide/hexadecyltrimethylammonium composite sponge (GO/HDTMA) was prepared investigated filtration material removal Cu(II) water. The formed porous GO/HDTMA highly stable in adsorption spontaneous exothermic, increasing with decreasing temperatures. showed good ability remove competing cations (K+, Na+, Ca2+, Mg2+) present. Five cycles adsorption-desorption-regeneration studies that, after adsorption, could be successfully regenerated repeated by using 1-M HCl solution desorption reagent. At sufficiently dose, excellent performance river containing different coexisting solutes. Finally, our 30-day column study revealed that is filtering conclusion, flow-through treatment applications removal.

参考文章(36)
Hongyu Wang, Bin Gao, Shenseng Wang, June Fang, Yingwen Xue, Kai Yang, Removal of Pb(II), Cu(II), and Cd(II) from aqueous solutions by biochar derived from KMnO4 treated hickory wood. Bioresource Technology. ,vol. 197, pp. 356- 362 ,(2015) , 10.1016/J.BIORTECH.2015.08.132
Lunhong Ai, Chunying Zhang, Zhonglan Chen, Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite. Journal of Hazardous Materials. ,vol. 192, pp. 1515- 1524 ,(2011) , 10.1016/J.JHAZMAT.2011.06.068
G RAO, C LU, F SU, Sorption of divalent metal ions from aqueous solution by carbon nanotubes: A review Separation and Purification Technology. ,vol. 58, pp. 224- 231 ,(2007) , 10.1016/J.SEPPUR.2006.12.006
Jie Xie, Wenna Meng, Deyi Wu, Zhenjia Zhang, Hainan Kong, Removal of organic pollutants by surfactant modified zeolite: comparison between ionizable phenolic compounds and non-ionizable organic compounds. Journal of Hazardous Materials. ,vol. 231, pp. 57- 63 ,(2012) , 10.1016/J.JHAZMAT.2012.06.035
Berrin Tansel, John Sager, Tony Rector, Jay Garland, Richard F. Strayer, Lanfang Levine, Michael Roberts, Mary Hummerick, Jan Bauer, Significance of hydrated radius and hydration shells on ionic permeability during nanofiltration in dead end and cross flow modes Separation and Purification Technology. ,vol. 51, pp. 40- 47 ,(2006) , 10.1016/J.SEPPUR.2005.12.020
Zao-Sheng Wang, Hai-Nan Kong, De-Yi Wu, Reproductive toxicity of dietary copper to a saltwater cladoceran, Moina monogolica daday Environmental Toxicology and Chemistry. ,vol. 26, pp. 126- 131 ,(2007) , 10.1897/06-216R1.1
Wafa M. Algothmi, Narasimha Murthy Bandaru, Yang Yu, Joseph G. Shapter, Amanda V. Ellis, Alginate-graphene oxide hybrid gel beads: An efficient copper adsorbent material Journal of Colloid and Interface Science. ,vol. 397, pp. 32- 38 ,(2013) , 10.1016/J.JCIS.2013.01.051
Niyaz Mohammad Mahmoodi, Bagher Hayati, Mokhtar Arami, Christopher Lan, Adsorption of textile dyes on Pine Cone from colored wastewater: Kinetic, equilibrium and thermodynamic studies Desalination. ,vol. 268, pp. 117- 125 ,(2011) , 10.1016/J.DESAL.2010.10.007
Francesco Tisato, Cristina Marzano, Marina Porchia, Maura Pellei, Carlo Santini, Copper in diseases and treatments, and copper-based anticancer strategies. Medicinal Research Reviews. ,vol. 30, pp. 708- 749 ,(2009) , 10.1002/MED.20174