Intramolecular vibrational relaxation and spectra of CH and CD overtones in benzene and perdeuterobenzene

作者: Edwin L. Sibert , William P. Reinhardt , James T. Hynes

DOI: 10.1063/1.447805

关键词: Atomic physicsInfrared spectroscopyIntramolecular forceOvertoneComputational chemistryExcited stateSpectral lineVibrational energy relaxationFermi resonanceRelaxation (NMR)Chemistry

摘要: … panels in em -I), and FWHM bandwidths in cm -1 (for spectral … ,7 Bray and Berry,3 Heller and Mukamel,6 and RHB,2 in that … cm - I is consistent with a change in inverse mass from PH + …

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