Cloud Point Preconcentration and High Performance Liquid Chromatographic Determination of Polycyclic Aromatic Hydrocarbons with Fluorescence Detection

作者: Carmelo. Garcia Pinto , Jose Luis. Perwez Pavon , Bernardo. Moreno Cordero

DOI: 10.1021/AC00078A019

关键词: Cloud pointChemistryNonionic surfactantFluorescenceHigh-performance liquid chromatographyFluorescence spectrometryHydrocarbonChromatographySorption

摘要: In chromatographic analysis of polycyclic aromatic hydrocarbons (PAH), three important aspects must be taken into account: losses by sorption onto the containers, association with dissolved organic material, and need for high preconcentration factors. this work, fluorescence detection was used liquid after cloud point nonionic surfactant Triton X-114. Negligible PAH containers recoveries, even in presence considerable levels humic acids, are additional advantages proposed micelle-mediated methodology

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