Aqueous phase reforming of ethylene glycol on Pt/CeO2–ZrO2: effects of cerium to zirconium molar ratio
作者： Seongho Jeon , Hyungwon Ham , Young-Woong Suh , Jong Wook Bae
DOI: 10.1039/C5RA07124K
关键词: Crystallite 、 Oxide 、 Ethylene glycol 、 Platinum 、 Catalysis 、 Cerium 、 Dispersion (chemistry) 、 Inorganic chemistry 、 Zirconium 、 Materials science
摘要: The aqueous-phase reforming (APR) reaction of ethylene glycol was investigated on platinum-supported CeO2–ZrO2 mixed oxides with different molar ratios Ce/(Ce + Zr). main role the ratio Zr) found to be alter dispersion active platinum crystallites and concomitantly change hydrogen productivity stability. amounts surface oxygen species defect sites altered changed metal–support interactions between nano-scale vacancy CeO2–ZrO2. A larger a area were observed for Pt/CeO2–ZrO2 having 4 : 6, catalyst showed higher conversion by forming thermally stable through their strong surface.
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