Scientific and technical maturity of molten carbonate technology

作者: J. Robert Selman , Chia-Chin Chen

DOI: 10.1016/J.IJHYDENE.2012.06.016

关键词: Hybrid systemSolid fuelBattery (electricity)Molten carbonate fuel cellIntrinsic kineticsFuel cellsMaturity (finance)Process engineeringEnvironmental scienceCarbonate

摘要: Abstract The molten carbonate fuel cell (MCFC) is sometimes referred to as a “mature” technology. Thereby implied that further development of the MCFC may not be expected yield innovation in technology and thereby diversity applications. However, for clear view role tomorrow's energy systems it makes more sense distinguish between “scientific maturity” “technical maturity”. These concepts are discussed with special reference commercial prospects MCFC, well cells general. Of interest two cases where relative “maturity” or “immaturity” have impact on potential applications, either retarding accelerating development. first case fed by carbon, is, solid fuel, semi-solid sludge, such biocarbon. optimal design hindered immaturity”, specifically, lack insight intrinsic kinetics these “substrates” carbonate. An illustration provided difficulty interpreting open-circuit measurements carbon second one-sided emphasis scale-up cells, whereas scale-down (miniaturization) has much offer. A consequence this immaturity” that, initially, there was little small hybrid employing small-scale other components batteries, PV (super)capacitors. This lag now finally being overcome. Some conceptual practical examples cell/battery SOFC given.

参考文章(14)
Hubert Gasteiger, Wolf Vielstich, Arnold Lamm, Handbook of fuel cells : fundamentals technology and applications Wiley. ,(2003)
Y. Mugikura, Stack material and stack design Handbook of Fuel Cells. ,(2010) , 10.1002/9780470974001.F306076
Ping-Hsun Hsieh, J. Robert Selman, Stephen J. McPhail, Molten Carbonate Fuel Cells Fuel Cells in the Waste-to-Energy Chain. pp. 97- 107 ,(2012) , 10.1007/978-1-4471-2369-9_6
John F. Cooper, J. Robert Selman, Analysis of the carbon anode in direct carbon conversion fuel cells International Journal of Hydrogen Energy. ,vol. 37, pp. 19319- 19328 ,(2012) , 10.1016/J.IJHYDENE.2012.03.095
Chia-Chin Chen, Toru Maruyama, Ping-Hsun Hsieh, J. Robert Selman, Wetting Behavior of Carbon in Molten Carbonate Journal of The Electrochemical Society. ,vol. 159, ,(2012) , 10.1149/2.022210JES
Kas Hemmes, Michel Cassir, A Theoretical Study of the Carbon/Carbonate/Hydroxide (Electro-) Chemical System in a Direct Carbon Fuel Cell Journal of Fuel Cell Science and Technology. ,vol. 8, pp. 051005- ,(2011) , 10.1115/1.4003750
D. G. Vutetakis, D. R. Skidmore, H. J. Byker, Electrochemical Oxidation of Molten Carbonate‐Coal Slurries Journal of The Electrochemical Society. ,vol. 134, pp. 3027- 3035 ,(1987) , 10.1149/1.2100334
Daniel J. Brett, Patricia Aguiar, Nigel P. Brandon, Ian Coop, Jason Dueck, Roy C. Galloway, Oliver Grande, Gary W. Hayes, Ken Lillie, Chris Mellors, Scott Thompson, Roger Tilley, Tony Wood, Operational Experience of an IT-SOFC / Battery Hybrid System for Automotive Applications ECS Transactions. ,vol. 7, pp. 113- 122 ,(2007) , 10.1149/1.2729080