Electrochemical oxidation of quercetin in the presence of benzenesulfinic acids
作者： D Nematollahi , M Malakzadeh
DOI: 10.1016/S0022-0728(03)00188-8
关键词: Inorganic chemistry 、 Sulfonyl 、 Electrochemistry 、 Cyclic voltammetry 、 Nuclear chemistry 、 Reaction mechanism 、 Chemistry 、 Michael reaction 、 Acetonitrile 、 Nucleophile 、 Coulometry
摘要: Electrochemical oxidation of quercetin has been studied in the absence and presence benzenesulfinic acids as nucleophiles an acetonitrile+water mixture, using cyclic voltammetry controlled-potential coulometry. The results indicate that o-quinone derived from participates a Michael addition reaction with to form corresponding sulfonyl derivatives. electrochemical synthesis these derivatives successfully performed at carbon rod electrodes undivided cell good yield purity.
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