Vibrational energy transfer and reactivity in HO+CO collisions

作者: Gert D. Billing , J. T. Muckerman , H. G. Yu

DOI: 10.1063/1.1496474

关键词: Compounds of carbonMolecular physicsVibrational energy relaxationPotential energyPotential energy surfaceChemical reactionChemical kineticsChain reactionReactivity (chemistry)PhotochemistryChemistry

摘要: The rate-constants for vibrational energy transfer and chemical reaction have been calculated using a recently modified potential surface.

参考文章(62)
John J. Lamb, Sidney W. Benson, Negative activation energies and curved Arrhenius plots. 2. Hydroxyl + carbon monoxide The Journal of Physical Chemistry. ,vol. 88, pp. 6435- 6441 ,(1984) , 10.1021/J150669A074
Charles D. Jonah, William A. Mulac, Philip Zeglinski, Rate constants for the reaction of hydroxyl + carbon monoxide, hydroxyl-d + carbon monoxide, and hydroxyl + methane as a function of temperature The Journal of Physical Chemistry. ,vol. 88, pp. 4100- 4104 ,(1984) , 10.1021/J150662A049
H. Niki, P. D. Maker, C. M. Savage, L. P. Breitenbach, Fourier transform infrared spectroscopic study of the kinetics for the hydroxyl radical reaction of 13C16O-carbon monoxide and 12C18O-carbon monoxide The Journal of Physical Chemistry. ,vol. 88, pp. 2116- 2119 ,(1984) , 10.1021/J150654A034
Ralph E. Weston, Anomalous or Mass-Independent Isotope Effects. Chemical Reviews. ,vol. 99, pp. 2115- 2136 ,(1999) , 10.1021/CR9800154
Kurt M. Christoffel, Joel M. Bowman, RRKM Theory beyond the Separable Harmonic Approximation: The HCO2 → H + CO2 Unimolecular Decomposition Journal of Physical Chemistry A. ,vol. 103, pp. 3020- 3030 ,(1999) , 10.1021/JP9843961
V. Lissianski, H. Yang, Z. Qin, M.R. Mueller, K.S. Shin, W.C. Gardiner, High-temperature measurements of the rate coefficient of the H + CO2 → CO + OH reaction Chemical Physics Letters. ,vol. 240, pp. 57- 62 ,(1995) , 10.1016/0009-2614(95)00496-Q
W. B. Demore, Rate constant for the OH + CO reaction: Pressure dependence and the effect of oxygen International Journal of Chemical Kinetics. ,vol. 16, pp. 1187- 1200 ,(1984) , 10.1002/KIN.550161003
S. I. Ionov, G. A. Brucker, C. Jaques, L. Valachovic, C. Wittig, Subpicosecond OH production from photoexcited CO2–HI complexes Journal of Chemical Physics. ,vol. 97, pp. 9486- 9489 ,(1992) , 10.1063/1.463275
Yumin Li, Joseph S. Francisco, High level ab initio studies on the excited states of HOCO radical Journal of Chemical Physics. ,vol. 113, pp. 7963- 7970 ,(2000) , 10.1063/1.1316011