Electrochemical aspects of Pt–Cu and Cu modified boron‐doped diamond

作者: Christos K. Mavrokefalos , Geoffrey W. Nelson , Christopher G. Poll , Richard G. Compton , John S. Foord

DOI: 10.1002/PSSA.201532163

关键词: ElectrodeCatalysisMethanolMaterials scienceSelectivityBoron doped diamondInorganic chemistryDiamondFoulingElectrochemistry

摘要: The synthesis of boron-doped diamond (BDD) electrodes, decorated with Pt–Cu or pure Cu nanoparticles is described in this study. A two-step electrochemical method involving the electrodeposition Cu, followed by Pt was used to synthesise former. activity Pt–Cu/BDD electrode evaluated towards methanol oxidation and compared catalytic Pt/BDD itself. Higher current densities less fouling at catalysts during seen alone. Also, a simple cost effective modify BDD using explored. High sensitivity response glucose KOH observed as well good reproducibility stability. Selectivity Cu/BDD presence low concentrations interfering species.

参考文章(59)
Xingbo Ge, Luyang Chen, Jianli Kang, Takeshi Fujita, Akihiko Hirata, Wei Zhang, Jianhua Jiang, Mingwei Chen, A Core‐Shell Nanoporous Pt‐Cu Catalyst with Tunable Composition and High Catalytic Activity Advanced Functional Materials. ,vol. 23, pp. 4156- 4162 ,(2013) , 10.1002/ADFM.201300114
A. M. Feltham, Michael Spiro, Platinized platinum electrodes Chemical Reviews. ,vol. 71, pp. 177- 193 ,(1971) , 10.1021/CR60270A002
Chiajen Hsu, Chienwen Huang, Yaowu Hao, Fuqiang Liu, Synthesis of highly active and stable Au-PtCu core-shell nanoparticles for oxygen reduction reaction Physical Chemistry Chemical Physics. ,vol. 14, pp. 14696- 14701 ,(2012) , 10.1039/C2CP42716H
Yu.V. Pelskov, A.Ya. Sakharova, M.D. Krotova, L.L. Bouilov, B.V. Spitsyn, Photoelectrochemical properties of semiconductor diamond Journal of Electroanalytical Chemistry. ,vol. 228, pp. 19- 27 ,(1987) , 10.1016/0022-0728(87)80093-1
Christine M. Welch, Andrew O. Simm, Richard G. Compton, Oxidation of Electrodeposited Copper on Boron Doped Diamond in Acidic Solution: Manipulating the Size of Copper Nanoparticles Using Voltammetry Electroanalysis. ,vol. 18, pp. 965- 970 ,(2006) , 10.1002/ELAN.200603493
A Pozio, M De Francesco, A Cemmi, F Cardellini, L Giorgi, Comparison of high surface Pt/C catalysts by cyclic voltammetry Journal of Power Sources. ,vol. 105, pp. 13- 19 ,(2002) , 10.1016/S0378-7753(01)00921-1
Min Wei, Chiaki Terashima, Mei Lv, Akira Fujishima, Zhong-Ze Gu, Boron-doped diamond nanograss array for electrochemical sensors. Chemical Communications. pp. 3624- 3626 ,(2009) , 10.1039/B903284C
L. Ley, S. Kowalczyk, R. Pollak, D. A. Shirley, X-Ray Photoemission Spectra of Crystalline and Amorphous Si and Ge Valence Bands Physical Review Letters. ,vol. 29, pp. 1088- 1092 ,(1972) , 10.1103/PHYSREVLETT.29.1088
Peter Strasser, Shirlaine Koh, Toyli Anniyev, Jeff Greeley, Karren More, Chengfei Yu, Zengcai Liu, Sarp Kaya, Dennis Nordlund, Hirohito Ogasawara, Michael F. Toney, Anders Nilsson, Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Nature Chemistry. ,vol. 2, pp. 454- 460 ,(2010) , 10.1038/NCHEM.623