Fluid catalytic cracking: modelling of an industrial riser
作者： F. Van Landeghem , D. Nevicato , I. Pitault , M. Forissier , P. Turlier
DOI: 10.1016/0926-860X(95)00309-6
关键词: Fluid catalytic cracking 、 Kinetic energy 、 Cracking 、 Hydrogen transfer 、 Mechanics 、 Alkane 、 Pitot tube 、 Catalysis 、 Flow (psychology) 、 Chemistry
摘要: Abstract The functioning of the riser catalytic cracking units was simulated using a new kinetic model reactions and an accurate description gas catalyst hydrodynamics in section. is based on molecular hydrogen transfer reactions. It may be seen as intermediate between simple lumping cuts ‘single events’ method. Chemical lumps, such alkanes, alkenes, cycloalkanes, alkenic cycloalkanes aromatics, are defined different cuts. Kinetic constants determined from experimental results obtained laboratory scale tubular reactor (M.A.T). data solid flow assessed by various techniques: isokinetic sampling, Pitot probe, γ-ray tomography tracing cold set-up or industrial risers. were compared with yields.
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M. Guisnet, P. Magnoux, Coking and deactivation of zeolites: Influence of the Pore Structure Applied Catalysis. ,vol. 54, pp. 1- 27 ,(1989) , 10.1016/S0166-9834(00)82350-7
D. Nevicato, I. Pitault, M. Forissier, J.R. Bernard, The activity decay of cracking catalysts: chemical and structural deactivation by coke Studies in Surface Science and Catalysis. ,vol. 88, pp. 249- 256 ,(1994) , 10.1016/S0167-2991(08)62747-0
M. Forissier, J.R. Bernard, Deactivation of Cracking Catalysts with Vacuum Gas Oils Studies in Surface Science and Catalysis. ,vol. 68, pp. 359- 366 ,(1991) , 10.1016/S0167-2991(08)62655-5
Ajit V. Sapre, Frederick J. Krambeck, Chemical Reactions in Complex Mixtures: The Mobil Workshop ,(2012)
M.P. Martin, C. Derouin, P. Turlier, M. Forissier, G. Wild, J.R. Bernard, Catalytic cracking in riser reactors : core-annulus and elbow effects Chemical Engineering Science. ,vol. 47, pp. 2319- 2324 ,(1992) , 10.1016/0009-2509(92)87054-T
Sudhir V. Golikeri, Dan Luss, Aggregation of many coupled consecutive first order reactions Chemical Engineering Science. ,vol. 29, pp. 845- 855 ,(1974) , 10.1016/0009-2509(74)80204-6
Wu Feng, Erik Vynckier, Gilbert F. Froment, Single-event kinetics of catalytic cracking Industrial & Engineering Chemistry Research. ,vol. 32, pp. 2997- 3005 ,(1993) , 10.1021/IE00024A007
R. J. Quann, S. B. Jaffe, Structure-oriented lumping: describing the chemistry of complex hydrocarbon mixtures Industrial & Engineering Chemistry Research. ,vol. 31, pp. 2483- 2497 ,(1992) , 10.1021/IE00011A013
M. Azzi, P. Turlier, J.R. Bernard, L. Garnero, Mapping solid concentration in a circulating fluid bed using gammametry Powder Technology. ,vol. 67, pp. 27- 36 ,(1991) , 10.1016/0032-5910(91)80023-C
R. A. Pachovsky, B. W. Wojciechowski, Theoretical interpretation of gas oil conversion data on an x-sieve catalyst The Canadian Journal of Chemical Engineering. ,vol. 49, pp. 365- 369 ,(1971) , 10.1002/CJCE.5450490311