Synthesis of Molybdenum Oxide Nanohybrids as Efficient Catalysts in Oxidation of Alcohols

作者: Maryam Afsharpour , Alireza Mahjoub , Mostafa M Amini , None

DOI: 10.1007/S10904-009-9285-5

关键词: FabricationHybrid materialAlcohol oxidationInorganic chemistryScanning electron microscopeCatalysisMaterials scienceIntercalation (chemistry)ThermogravimetryOxide

摘要: Novel layered materials based on molybdenum oxide have been synthesized using three amino-carboxylate ligands; terephetalic acid, p-aminobezoic acid and diaminobenzene. On the basis of X-ray diffraction, scanning electron microscopy, thermogravimetry, infrared results, insertion organic ligands into interlayer space has proposed. Moreover, influence guests structure also their catalytic performance are discussed. Furthermore, fabrication nanostructured is achieved by calcinations these hybrid at 600 °C. Somewhat oriented nanoplatelets viewed with different activity.

参考文章(29)
Ye Zhao, Jingguo Liu, Ya Zhou, Zhengjun Zhang, Yonghua Xu, H Naramoto, S Yamamoto, Preparation of MoO3 nanostructures and their optical properties Journal of Physics: Condensed Matter. ,vol. 15, ,(2003) , 10.1088/0953-8984/15/35/101
S. T. Oyama, R. Radhakrishnan, M. Seman, J. N. Kondo, K. Domen, K. Asakura, Control of Reactivity in C−H Bond Breaking Reactions on Oxide Catalysts: Methanol Oxidation on Supported Molybdenum Oxide Journal of Physical Chemistry B. ,vol. 107, pp. 1845- 1852 ,(2003) , 10.1021/JP0220276
H. C. Zeng, W. K. Ng, L. H. Cheong, F. Xie, R. Xu, Insertion Direction of Hydrogen in Protonation of α-MoO3 Journal of Physical Chemistry B. ,vol. 105, pp. 7178- 7181 ,(2001) , 10.1021/JP010177V
Hideyuki Tagaya, Kensuke Ara, Jun-ichi Kadokawa, Masa Karasu, Koji Chiba, Intercalation of organic compounds in the layered host lattice MoO3 Journal of Materials Chemistry. ,vol. 4, pp. 551- 555 ,(1994) , 10.1039/JM9940400551
Cheng Dong, POwderX: Windows-95-based program for powder X-ray diffraction data processing Journal of Applied Crystallography. ,vol. 32, pp. 838- 838 ,(1999) , 10.1107/S0021889899003039
Wan-sheng You, Xin Guo, Xiao-li Yu, Cui-ying Huang, Lan-cui Zhang, Zhen-gang Sun, A novel 1D molybdenum oxide ribbon bridged by pyridine-4-carboxylic ligands: [(C6H4NO2) Mo2O5OH] Inorganic Chemistry Communications. ,vol. 10, pp. 23- 26 ,(2007) , 10.1016/J.INOCHE.2006.09.003
Pamela J. Hagrman, Robert L. LaDuca,, H.-J. Koo, Randy Rarig,, Robert C. Haushalter, Myung-Hwan Whangbo, Jon Zubieta, Ligand Influences on the Structures of Molybdenum Oxide Networks Inorganic Chemistry. ,vol. 39, pp. 4311- 4317 ,(2000) , 10.1021/IC000496L
Sakae Takenaka, Tsunehiro Tanaka, Takuzo Funabiki, Satohiro Yoshida, Structures of Molybdenum Species in Silica-Supported Molybdenum Oxide and Alkali-Ion-Modified Silica-Supported Molybdenum Oxide Journal of Physical Chemistry B. ,vol. 102, pp. 2960- 2969 ,(1998) , 10.1021/JP980134N
Soumen Dasgupta, Monika Agarwal, Arunabha Datta, Long chain alkyl amine templated synthesis of a mesostructured lamellar vanadium phosphate phase Journal of Materials Chemistry. ,vol. 12, pp. 162- 164 ,(2002) , 10.1039/B109472F