Olfactory perception of cysteine-S-conjugates from fruits and vegetables.

作者: Christian Starkenmann , Benedicte Le Calvé , Yvan Niclass , Isabelle Cayeux , Sabine Beccucci

DOI: 10.1021/JF801873H

关键词: Fruits and vegetablesCysteinePepperOdorSulfurSalivaWineChemistrySensory analysisFood science

摘要: Volatile sulfur compounds have a low odor threshold, and their presence at microgram per kilogram levels in fruits vegetables influences quality. Sensory analysis demonstrates that naturally occurring, odorless cysteine−S-conjugates such as S-(R/S)-3-(1-hexanol)-l-cysteine wine, S-(1-propyl)-l-cysteine onion, S-((R/S)-2-heptyl)-l-cysteine bell pepper are transformed into volatile thiols the mouth by microflora. The time delay smelling these was 20−30 s, persistent perception of occurred for 3 min. free thiol anaerobes. acts reactor, adding another dimension to perception, saliva modulates flavors trapping thiols.

参考文章(7)
D. I. Carroll, I. Dzidic, E. C. Horning, R. N. Stillwell, Atmospheric Pressure Ionization Mass Spectrometry Applied Spectroscopy Reviews. ,vol. 17, pp. 337- 406 ,(1981) , 10.1080/05704928108060409
Kouichiro Tsuge, Mieko Kataoka, Yasuo Seto, Determination of S-methyl-, S-propyl-, and S-propenyl-L-cysteine sulfoxides by gas chromatography-mass spectrometry after tert-butyldimethylsilylation. Journal of Agricultural and Food Chemistry. ,vol. 50, pp. 4445- 4451 ,(2002) , 10.1021/JF020166E
Andrea Buettner, Influence of human salivary enzymes on odorant concentration changes occurring in vivo. 1. Esters and thiols. Journal of Agricultural and Food Chemistry. ,vol. 50, pp. 3283- 3289 ,(2002) , 10.1021/JF011586R
Takatoshi Tominaga, Catherine Peyrot des Gachons, Denis Dubourdieu, A new type of flavor precursors in Vitis vinifera L. cv. Sauvignon Blanc : S-Cysteine conjugates Journal of Agricultural and Food Chemistry. ,vol. 46, pp. 5215- 5219 ,(1998) , 10.1021/JF980481U
Takatoshi Tominaga, Anton Furrer, Robert Henry, Denis Dubourdieu, Identification of new volatile thiols in the aroma of Vitis vinifera L. var. Sauvignon blanc wines Flavour and Fragrance Journal. ,vol. 13, pp. 159- 162 ,(1998) , 10.1002/(SICI)1099-1026(199805/06)13:3<159::AID-FFJ709>3.0.CO;2-7
Christian Starkenmann, Yvan Niclass, Myriam Troccaz, Anthony J. Clark, Identification of the precursor of (S)-3-methyl-3-sulfanylhexan-1-ol, the sulfury malodour of human axilla sweat. Chemistry & Biodiversity. ,vol. 2, pp. 705- 716 ,(2005) , 10.1002/CBDV.200590048