A New Investigation on Asphaltene Removal from Crude Oil: Experimental Study in Flow–Loop System Using Maghemite Nanoparticles

作者: B. Mirzayi , M. Younesi , A. Nematollahzadeh

DOI: 10.1134/S0965544121060037

关键词: Precipitation (chemistry)MaghemiteOrganic compoundChemical engineeringFerrousFerricAsphalteneAdsorptionNanoparticleMaterials science

摘要: Asphaltene is the heaviest organic compound in crude oils that its precipitation and deposition cause many negative effects on oil production such as an overall decrease rate increase operating costs. Nanoparticle technology a rapidly growing field may supply alternative novel technique for heavy upgrading recovery. As asphaltene depletion by nanoparticles system close to reality has not been studied yet, this work adsorption process was investigated flow–loop resemble real process. To end, co-precipitation of ferric ferrous ions method applied synthesis maghemite (γ-Fe2O3) nanoparticles. The synthesized (MNPs) were removal from samples system. influence different factors contact time, dose nanoparticles, flow velocity investigated. results mode experiment indicated onto MNPs increases with increasing velocity, MNPs. Kinetic experiments also showed follows nonlinear Thomas model equilibrium could be achieved less than 4 h.

参考文章(45)
Belal J. Abu Tarboush, Maen M. Husein, Adsorption of asphaltenes from heavy oil onto in situ prepared NiO nanoparticles. Journal of Colloid and Interface Science. ,vol. 378, pp. 64- 69 ,(2012) , 10.1016/J.JCIS.2012.04.016
Nashaat N. Nassar, Asphaltene Adsorption onto Alumina Nanoparticles: Kinetics and Thermodynamic Studies Energy & Fuels. ,vol. 24, pp. 4116- 4122 ,(2010) , 10.1021/EF100458G
Nashaat N. Nassar, Azfar Hassan, Pedro Pereira-Almao, Comparative oxidation of adsorbed asphaltenes onto transition metal oxide nanoparticles Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 384, pp. 145- 149 ,(2011) , 10.1016/J.COLSURFA.2011.03.049
Behruz Mirzayi, Nazila Naghdi Shayan, Adsorption kinetics and catalytic oxidation of asphaltene on synthesized maghemite nanoparticles Journal of Petroleum Science and Engineering. ,vol. 121, pp. 134- 141 ,(2014) , 10.1016/J.PETROL.2014.06.031
M. Jamialahmadi, B. Soltani, H. Müller-Steinhagen, D. Rashtchian, Measurement and prediction of the rate of deposition of flocculated asphaltene particles from oil International Journal of Heat and Mass Transfer. ,vol. 52, pp. 4624- 4634 ,(2009) , 10.1016/J.IJHEATMASSTRANSFER.2009.01.049
Tímea Pernyeszi, Ágnes Patzkó, Ottó Berkesi, Imre Dékány, ASPHALTENE ADSORPTION ON CLAYS AND CRUDE OIL RESERVOIR ROCKS Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 137, pp. 373- 384 ,(1998) , 10.1016/S0927-7757(98)00214-3
Nashaat N. Nassar, Azfar Hassan, Pedro Pereira-Almao, Application of Nanotechnology for Heavy Oil Upgrading: Catalytic Steam Gasification/Cracking of Asphaltenes Energy & Fuels. ,vol. 25, pp. 1566- 1570 ,(2011) , 10.1021/EF2001772
Xiong Liu, James G. Worden, Qun Huo, Joseph P. Brennan, Kinetic study of gold nanoparticle growth in solution by Brust-Schiffrin reaction. Journal of Nanoscience and Nanotechnology. ,vol. 6, pp. 1054- 1059 ,(2006) , 10.1166/JNN.2006.138
B. Mirzayi, M. Vafaie-Sefti, S. A. Mousavi-Dehghani, M. Fasih, G. A. Mansoori, The Effects of Asphaltene Deposition on Unconsolidated Porous Media Properties during Miscible Natural Gas Flooding Petroleum Science and Technology. ,vol. 26, pp. 231- 243 ,(2008) , 10.1080/10916460600806143
Nael Zaki, Peter-Christoph Schoriing, Iradj Rahimian, Effect of asphaltene and resins on the stability of water-in-waxy oil emulsions Petroleum Science and Technology. ,vol. 18, pp. 945- 963 ,(2000) , 10.1080/10916460008949884