A theoretical and experimental study on optical limiting in platinum nanoparticles

作者: Shiliang Qu , Yinglin Song , Hanfan Liu , Yuxiao Wang , Yachen Gao

DOI: 10.1016/S0030-4018(02)01134-3

关键词: Platinum nanoparticlesTransition metalNanosecondPlatinumExcitationNanoparticleOpticsExtinction (optical mineralogy)Materials scienceNonlinear optics

摘要: Optical limiting performance of PVP-stabilized platinum nanoparticles in methanol is investigated with 8 ns pulses at 532 nm. The experimental results show that the possess strong optical effect. We propose a theoretical model based on Mie extinction theory to describe nonlinear (OL) behavior metal nanoparticles. analysis and main mechanism for OL can be attributed interband transition during excitation nanosecond pulses.

参考文章(20)
Michael Vollmer, Uwe Kreibig, Optical properties of metal clusters ,(1995)
Reji Philip, G. Ravindra Kumar, N. Sandhyarani, T. Pradeep, Picosecond optical nonlinearity in monolayer-protected gold, silver, and gold-silver alloy nanoclusters Physical Review B. ,vol. 62, pp. 13160- 13166 ,(2000) , 10.1103/PHYSREVB.62.13160
Radu G. Ispasoiu, Lajos Balogh, Oleg P. Varnavski, Donald A. Tomalia, Goodson, Large Optical Limiting from Novel Metal-Dendrimer Nanocomposite Materials Journal of the American Chemical Society. ,vol. 122, pp. 11005- 11006 ,(2000) , 10.1021/JA0015646
Shiliang Qu, Yinglin Song, Chimin Du, Yuxiao Wang, Yachen Gao, Shutian Liu, Yuliang Li, Daoben Zhu, Nonlinear optical properties in three novel nanocomposites with gold nanoparticles Optics Communications. ,vol. 196, pp. 317- 323 ,(2001) , 10.1016/S0030-4018(01)01375-X
Misao Sasaki, Takahiro Tanaka, Kazuhiro Yamamoto, Jun'ichi Yokoyama, Quantum state inside a vacuum bubble and the creation of an open universe Physics Letters B. ,vol. 317, pp. 510- 516 ,(1993) , 10.1016/0370-2693(93)91364-S
F. Hache, D. Ricard, C. Flytzanis, U. Kreibig, The optical kerr effect in small metal particles and metal colloids: The case of gold Applied Physics A. ,vol. 47, pp. 347- 357 ,(1988) , 10.1007/BF00615498
Jason E. Riggs, David B. Walker, David L. Carroll, Ya-Ping Sun, Optical Limiting Properties of Suspended and Solubilized Carbon Nanotubes§ The Journal of Physical Chemistry B. ,vol. 104, pp. 7071- 7076 ,(2000) , 10.1021/JP0011591
Weixia Tu, Hanfan Liu, Rapid synthesis of nanoscale colloidal metalclusters by microwave irradiation Journal of Materials Chemistry. ,vol. 10, pp. 2207- 2211 ,(2000) , 10.1039/B002232M
W. C. Mundy, J. A. Roux, A. M. Smith, Mie scattering by spheres in an absorbing medium. Journal of the Optical Society of America. ,vol. 64, pp. 1593- 1597 ,(1974) , 10.1364/JOSA.64.001593
Lee W. Tutt, Thomas F. Boggess, A review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials Progress in Quantum Electronics. ,vol. 17, pp. 299- 338 ,(1993) , 10.1016/0079-6727(93)90004-S