Honeycomb-structured catalysts for the selective partial oxidation of H2S

作者: Vincenzo Palma , Daniela Barba , Vincenzo Gerardi

DOI: 10.1016/J.JCLEPRO.2015.07.105

关键词: Deposition (phase transition)CordieriteCatalysisInorganic chemistrySulfurPartial oxidationVanadiumSelectivityChemical engineeringMaterials scienceMonolith

摘要: The reaction of H 2 S selective partial oxidation to elemental sulfur was studied on cordierite honeycomb-structured catalysts in the range of temperature of 150–200° C. The preparation procedure of catalytic cordierite monoliths has been studied, from the washcoating with CeO 2 to the deposition of V 2 O 5 by wet impregnation. Two different preparation washcoating procedures deposition were studied: in one case the washcoat had been already added with the salts precursors of the active species (joint impregnation method), in other case the …

参考文章(19)
J.D. McMillan, Pretreatment of lignocellulosic biomass ACS symposium series (USA). ,(1994)
T. Weingand, D.H. Gregory, H. Knözinger, W. Daniell, A. Ponchel, S. Kuba, F. Anderle, Characterization and catalytic behavior of VOx-CeO2 catalysts for the oxidative dehydrogenation of propane Topics in Catalysis. ,vol. 20, pp. 65- 74 ,(2002) , 10.1023/A:1016399315511
L.X. Zhang, C.B. Wang, B. Song, Carbon emission reduction potential of a typical household biogas system in rural China Journal of Cleaner Production. ,vol. 47, pp. 415- 421 ,(2013) , 10.1016/J.JCLEPRO.2012.06.021
T. Alexander Nijhuis, Annemarie E. W. Beers, Theo Vergunst, Ingrid Hoek, Freek Kapteijn, Jacob A. Moulijn, Preparation of monolithic catalysts Catalysis Reviews-science and Engineering. ,vol. 43, pp. 345- 380 ,(2001) , 10.1081/CR-120001807
ME Montingelli, Silvia Tedesco, AG Olabi, J Stokes, Biogas production from algal biomass: A review Renewable & Sustainable Energy Reviews. ,vol. 43, pp. 961- 972 ,(2015) , 10.1016/J.RSER.2014.11.052
Martina Poeschl, Shane Ward, Philip Owende, Environmental impacts of biogas deployment – Part II: life cycle assessment of multiple production and utilization pathways Journal of Cleaner Production. ,vol. 24, pp. 184- 201 ,(2012) , 10.1016/J.JCLEPRO.2011.10.030
Sena Yasyerli, Gulsen Dogu, Irfan Ar, Timur Dogu, Dynamic analysis of removal and selective oxidation of H2S to elemental sulfur over Cu–V and Cu–V–Mo mixed oxides in a fixed bed reactor Chemical Engineering Science. ,vol. 59, pp. 4001- 4009 ,(2004) , 10.1016/J.CES.2004.03.045
Ronald M. Heck, Suresh Gulati, Robert J. Farrauto, The application of monoliths for gas phase catalytic reactions Chemical Engineering Journal. ,vol. 82, pp. 149- 156 ,(2001) , 10.1016/S1385-8947(00)00365-X
Murat Mirata, Helen Nilsson, Jaakko Kuisma, Production systems aligned with distributed economies: Examples from energy and biomass sectors Journal of Cleaner Production. ,vol. 13, pp. 981- 991 ,(2005) , 10.1016/J.JCLEPRO.2004.12.018