Microwave Zeeman Effect of Formaldehyde

作者: Kunitaka Kondo , Hiromasa Hirakawa , Akira Miyahara , Takeshi Oka , Koichi Shimoda

DOI: 10.1143/JPSJ.15.303

关键词: PhysicsMagnetic fieldAnalytical chemistryZeeman effectAbsorption spectroscopyQuantum numberMoleculeTensorMicrowaveFormaldehydeAtomic physicsGeneral Physics and Astronomy

摘要: Zeeman effects in the absorption spectra of formaldehyde H 2 CO, HDCO, and D CO were studied microwave region with magnetic field 1500∼300 oersteds. The effective g -values several rotational states elements -tensor a , b c these molecules determined. Dependences on quantum numbers J τ consistent among isotopically substituted molecules. components -tensors have been found to be =2.86±0.04 for 2.00±0.05 1.46±0.05 CO. They are extraordinarily large compared those other already known. A brief qualitative interpretation is given.

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