Determination of accessible amino groups on surfaces by chemical derivatization with 3,5-bis(trifluoromethyl)phenyl isothiocyanate and XPS/NEXAFS analysis

作者: Nora Graf , Andreas Lippitz , Thomas Gross , Falko Pippig , Andreas Holländer

DOI: 10.1007/S00216-009-3233-7

关键词: SilanolPhenyl isothiocyanateSubstrate (chemistry)X-ray photoelectron spectroscopyBiomoleculeDerivatizationTrifluoromethylSiloxaneOrganic chemistryChemistry

摘要: … In contrast to the aforementioned reactions, we used a reagent with an isothiocyanate group, a functionality widely used in biochemistry for labeling of amines, eg, in peptides or …

参考文章(54)
G. Beamson, D. Briggs, High resolution XPS of organic polymers The Scienta ESCA 300 Database. ,(1992)
R. Wilken, A. Holländer, J. Behnisch, Vacuum Ultraviolet Photolysis of Polyethylene, Polypropylene, and Polystyrene Plasmas and Polymers. ,vol. 7, pp. 185- 205 ,(2002) , 10.1023/A:1015217900896
K.H Hallmeier, D Mayer, R Szargan, Characterization of organic adsorbates of CdS(101̄0) surfaces by SXPS and XANES investigation Journal of Electron Spectroscopy and Related Phenomena. ,vol. 96, pp. 245- 251 ,(1998) , 10.1016/S0368-2048(98)00243-6
Mark D. Ellison, Robert J. Hamers, Adsorption of Phenyl Isothiocyanate on Si(001): A 1,2-Dipolar Surface Addition Reaction Journal of Physical Chemistry B. ,vol. 103, pp. 6243- 6251 ,(1999) , 10.1021/JP990010Q
Sabrina Devouge, Claudio Salvagnini, Jacqueline Marchand-Brynaert, A practical molecular clip for immobilization of receptors and biomolecules on devices’ surface: Synthesis, grafting protocol and analytical assay Bioorganic & Medicinal Chemistry Letters. ,vol. 15, pp. 3252- 3256 ,(2005) , 10.1016/J.BMCL.2005.04.071
Xiaofeng Wang, Xiaoqing Liu, Linfei Lai, Siyue Li, Jian Weng, Zhimin Zhou, Qiang Cui, Xin Chen, Minyuan Cao, Qiqing Zhang, Syntheses, Properties and Electrochemical Activity of Carbon Microtubes Modified with Amino Groups Advanced Functional Materials. ,vol. 18, pp. 1809- 1823 ,(2008) , 10.1002/ADFM.200701020
Betty Cranfill, Preparation of ultrathin polyethylene foils by film casting. Review of Scientific Instruments. ,vol. 49, pp. 264- 265 ,(1978) , 10.1063/1.1135384
David P. Hansell, Robert F. Hudson, The reaction of oximes and phenols with acyl isothiocyanates; an example of regioselectivity Journal of The Chemical Society, Chemical Communications. pp. 1405- 1406 ,(1985) , 10.1039/C39850001405
Pil-Sook Grace Kim, N.O. Petersen, T.K. Sham, Y.F. Hu, Soft X-ray excited optical luminescence (XEOL) studies of fluorescein isothiocyanate (FITC) and FITC-labeled proteins☆ Chemical Physics Letters. ,vol. 392, pp. 44- 49 ,(2004) , 10.1016/J.CPLETT.2004.05.048