Oxidation of dimethoxymethane in a jet-stirred reactor
作者： Catherine A Daly , John M Simmie , Philippe Dagaut , Michel Cathonnet
DOI: 10.1016/S0010-2180(01)00227-9
关键词: Propane 、 Dimethoxymethane 、 Methyl formate 、 Propene 、 Chemistry 、 Dimethyl ether 、 Inorganic chemistry 、 Hydrogen 、 Carbon monoxide 、 Methanol
摘要: Abstract The oxidation of dimethoxymethane has been investigated in a jet-stirred reactor at pressures 5.07 bar, temperatures 800 to 1200 K, and equivalence ratios 0.444, 0.889, 1.778. Concentration profiles carbon monoxide, dioxide, hydrogen, methane, formaldehyde, methanol, acetaldehyde, methyl formate, ethane, ethene, ethyne, propane, propene were obtained by probe sampling gas chromatography analysis. A detailed chemical kinetic model accounts quite well for the bulk measurements; lower end temperature scale it is necessary postulate very low activation energy decompositions dimethoxymethane, most probably surface-catalyzed reactions, one leading formaldehyde + dimethyl ether, other methanol acetaldehyde: H3COCH2OCH3 → H2CO H3COCH3 CH3OH CH3HCO
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sci-hub.se 参考文章(35)
T.H. Fleisch, A. Basu, M.J. Gradassi, J.G. Masin, Dimethyl ether: A fuel for the 21st century Studies in Surface Science and Catalysis. ,vol. 107, pp. 117- 125 ,(1997) , 10.1016/S0167-2991(97)80323-0
Bradley L. Edgar, Autoignition of Dimethyl Ether and Dimethoxy Methane Sprays at High Pressures SAE Technical Paper Series. ,vol. 106, pp. 625- 639 ,(1997) , 10.4271/971677
Keith D. Vertin, James M. Ohi, David W. Naegeli, Kenneth H. Childress, Gary P. Hagen, Chris I. McCarthy, Adelbert S. Cheng, Robert W. Dibble, Methylal and Methylal-Diesel Blended Fuels for Use in Compression-Ignition Engines SAE Technical Paper Series. ,(1999) , 10.4271/1999-01-1508
Catherine Daly, John M. Simmie, Michel Cathonnet, Philippe Dagaut, The oxidation and ignition of dimethylether from low to high temperature (500–1600 K): Experiments and kinetic modeling Symposium (International) on Combustion. ,vol. 27, pp. 361- 369 ,(1998) , 10.1016/S0082-0784(98)80424-4
Joyce Long, G. Skirrow, Reaction of methyl radicals with di-ethyl ether Transactions of the Faraday Society. ,vol. 58, pp. 1403- 1408 ,(1962) , 10.1039/TF9625801403
P Dagaut, M Cathonnet, J P Rouan, R Foulatier, A Quilgars, J C Boettner, F Gaillard, H James, A jet-stirred reactor for kinetic studies of homogeneous gas-phase reactions at pressures up to ten atmospheres (∼1 MPa) Journal of Physics E: Scientific Instruments. ,vol. 19, pp. 207- 209 ,(1986) , 10.1088/0022-3735/19/3/009
Alessandro Goldaniga, Tiziano Faravelli, Eliseo Ranzi, Philippe Dagaut, Michel Cathonnet, Oxidation of oxygenated octane improvers: MTBE, ETBE, DIPE, and TAME Symposium (International) on Combustion. ,vol. 27, pp. 353- 360 ,(1998) , 10.1016/S0082-0784(98)80423-2
H. J. Curran, W. J. Pitz, C. K. Westbrook, P. Dagaut, J-C Boettner, M. Cathonnet, A WIDE RANGE MODELING STUDY OF DIMETHYL ETHER OXIDATION International Journal of Chemical Kinetics. ,vol. 30, pp. 229- 241 ,(1998) , 10.1002/(SICI)1097-4601(1998)30:3<229::AID-KIN9>3.0.CO;2-U
P. Dagaut, M. Cathonnet, J. C. Boetiner, F. Gaillard, Kinetic modeling of propane oxidation Combustion Science and Technology. ,vol. 56, pp. 23- 63 ,(1987) , 10.1080/00102208708947080
Philippe Dagaut, David Voisin, Michel Cathonnet, Marguerite Mcguinness, John M. Simmie, The oxidation of ethylene oxide in a jet-stirred reactor and its ignition in shock waves Combustion and Flame. ,vol. 106, pp. 62- 68 ,(1996) , 10.1016/0010-2180(95)00229-4