Energy Balance in the Photochemistry of Benzene
作者： W. Albert Noyes , D. A. Harter
DOI: 10.1063/1.1840724
关键词: Angstrom 、 Photochemistry 、 Wavelength 、 Yield (chemistry) 、 Energy balance 、 Fluorescence 、 Benzene 、 Chemistry 、 Benzene vapor 、 Quantum 、 Atomic physics 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Quantum yields of triplet‐state formation in benzene vapor have been determined at several wavelengths by the method Cundall. From 2520 to 2668 A, values average about 0.63 if one excludes those a single wavelength 2535.5 A. At this higher value is obtained, and its possible significance briefly discussed. 2420 A yield small may be zero. Fluorescent scanned for ranges few Angstrom units from 2400 2600 Above there no significant change with wavelength. The trends these results are discussed, it pointed out that detailed discussion theory photochemistry has little because data now available not sufficient test any theory.
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sci-hub.se 参考文章(26)
P. W. Beck, D. V. Kniebes, H. E. Gunning, Reaction of Cyclohexane with Mercury‐6(3P1) Atoms The Journal of Chemical Physics. ,vol. 22, pp. 672- 677 ,(1954) , 10.1063/1.1740146
Eva Migirdicyan, Sydney Leach, La Photolyse de Quelques Composes Cycliques en Milieu Rigide Bulletin des Sociétés Chimiques Belges. ,vol. 71, pp. 845- 854 ,(2010) , 10.1002/BSCB.19620711138
E. E. Van Tamelen, S. P. Pappas, Chemistry of Dewar Benzene. 1,2,5-Tri-t-Butylbicyclo[2.2.0]Hexa-2,5-Diene Journal of the American Chemical Society. ,vol. 84, pp. 3789- 3791 ,(1962) , 10.1021/JA00878A054
Paul Sigal, Benzene d‐6‐Sensitized Photoisomerization of Butene‐2 at Low Pressures by Long‐Path Infrared Spectroscopy Journal of Chemical Physics. ,vol. 42, pp. 1953- 1957 ,(1965) , 10.1063/1.1696230
I. Unger, Triplet State of Fluorobenzene The Journal of Physical Chemistry. ,vol. 69, pp. 4284- 4289 ,(1965) , 10.1021/J100782A035
H. Ishikawa, W. Albert Noyes, Photosensitization by Benzene Vapor: Biacetyl. The Triplet State of Benzene Journal of Chemical Physics. ,vol. 37, pp. 583- 591 ,(1962) , 10.1063/1.1701379
W. Albert Noyes, W. A. Mulac, D. A. Harter, Some Aspects of the Photochemistry of Benzene Journal of Chemical Physics. ,vol. 44, pp. 2100- 2106 ,(1966) , 10.1063/1.1726987
T. S. Godfrey, G. Porter, Absorption spectrum of triplet benzene Transactions of the Faraday Society. ,vol. 62, pp. 7- 10 ,(1966) , 10.1039/TF9666200007
John A. Poole, The Fluorescence of Benzene and Benzene-d6 The Journal of Physical Chemistry. ,vol. 69, pp. 1343- 1347 ,(1965) , 10.1021/J100888A040
M. E. Bednas, D. S. Russell, A STUDY OF SILVER NITRATE SOLUTIONS IN GAS CHROMATOGRAPHY Canadian Journal of Chemistry. ,vol. 36, pp. 1272- 1276 ,(1958) , 10.1139/V58-185