The Mercury Photosensitized Polymerization of Acetylene
作者： D. J. Le Roy , E. W. R. Steacie
DOI: 10.1063/1.1723921
关键词: Temperature coefficient 、 Photochemistry 、 Nitric oxide 、 Chemistry 、 Polymerization 、 Mercury (element) 、 Acetylene 、 Quantum yield 、 Radical 、 Inorganic chemistry 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: An investigation has been made of the mercury (3P1) photosensitized polymerization acetylene. The is inhibited by nitric oxide and it concluded that free radicals are probably involved. quantum yield uninhibited reaction 4.5±1.2. Experiments over range 25°C to 300°C show temperature coefficient not large. A few measurements were also with Cd(3P1) Cd(1P1) atoms.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(14)
D. J. LeRoy, E. W. R. Steacie, The Mercury Photosensitized Reactions of Ethylene at High Temperatures The Journal of Chemical Physics. ,vol. 10, pp. 676- 682 ,(1942) , 10.1063/1.1723643
H. W. Melville, The mercury photosensitised polymerisation of acetylene Transactions of The Faraday Society. ,vol. 32, ,(1936) , 10.1039/TF936320258B
A. L. Marshall, THE PHOTOCHEMICAL FORMATION OF HYDROGEN PEROXIDE Journal of the American Chemical Society. ,vol. 54, pp. 4460- 4461 ,(1932) , 10.1021/JA01350A506
Joseph C. Jungers, Hugh S. Taylor, The Mercury Photosensitized Polymerization of Acetylene and Acetylene‐d2 The Journal of Chemical Physics. ,vol. 3, pp. 338- 340 ,(1935) , 10.1063/1.1749667
Mark Waldo Zemansky, Allan C. G. Mitchell, Resonance radiation and excited atoms ,(1934)
E. W. R. Steacie, D. J. LeRoy, The Quenching of Cadmium Resonance Radiation (3261A) by Hydrocarbons and Other Gases The Journal of Chemical Physics. ,vol. 11, pp. 164- 171 ,(1943) , 10.1063/1.1723821
D. P. Stevenson, Ionization and Dissociation by Electron Impact: Butene-1 Journal of the American Chemical Society. ,vol. 65, pp. 209- 212 ,(1943) , 10.1021/JA01242A019
D. J. LeRoy, E. W. R. Steacie, The Mercury Photosensitized Reactions of Ethylene Journal of Chemical Physics. ,vol. 9, pp. 829- 839 ,(1941) , 10.1063/1.1750853
E. W. R. Steacie, D. J. LeRoy, The Polymerization of Ethylene Photosensitized by 51P1 Cadmium Atoms The Journal of Chemical Physics. ,vol. 10, pp. 22- 34 ,(1942) , 10.1063/1.1723618
J. S. A. Forsyth, The reaction of free methyl radicals with nitric oxide Transactions of The Faraday Society. ,vol. 37, pp. 312- 318 ,(1941) , 10.1039/TF9413700312