A reduced kinetic mechanism for premixed CH3Cl/air flames
作者： K.Y. Lee , I.K. Puri
DOI: 10.1016/0010-2180(93)90154-U
关键词: Thermodynamics 、 Chemical reaction 、 Inorganic chemistry 、 Premixed flame 、 Reaction mechanism 、 Reaction rate 、 Chloride 、 Hydrogen 、 Steady state (chemistry) 、 Diffusion flame 、 Chemistry
摘要: Abstract A reduced chemical kinetic mechanism is developed in order to predict the flame phenomena associated with methyl chloride burning air. The mechanism, which consists of nine global steps, systematically derived from a detailed scheme involving 63 elementary steps. capable explicitly calculating concentration 15 species along C 1 and 2 pathways (including molecular nitrogen, acts as an inert), implicitly predicting ten species. Good agreement found between speeds predicted by mechanisms, experimental results obtained this laboratory. In addition, profiles are those mechanism. present study has been investigated for premixed flames stoichiometric mixtures air, its application should be limited same.
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