N2,S-versus N3,S-coordination in thiosemicarbazonate complexes: only a steric influence?
作者： José S. Casas , Eduardo E. Castellano , Javier Ellena , María S. García-Tasende , Agustín Sánchez
DOI: 10.1016/J.INOCHE.2004.08.001
关键词: Crystallography 、 Chemistry 、 Semicarbazone 、 Solid-state 、 Steric effects 、 Crystal structure 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Materials Chemistry
摘要: Abstract The factors that determine the formation of Nhydrazinic,S- or Niminic,S-coordinate thiosemicarbazonate complexes in solid state are examined light X-ray structure complex [PbPh2(EtGTSC)2] · H2O (HEtGTSC = ethylglyoxylate thiosemicarbazone).
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Cheolki Paek, Sang Ook Kang, Jaejung Ko, Patrick J. Carroll, Synthesis and Characterization of New Trinuclear Aluminum and Gallium Complexes of Bis(thiosemicarbazones). Single-Crystal Structure of (MeAl){CH2[C(Me)NNC(S)N(Me)]2}(AlMe2)2 Organometallics. ,vol. 16, pp. 1503- 1506 ,(1997) , 10.1021/OM9607917
Falguni Basuli, Shie-Ming Peng, Samaresh Bhattacharya, Steric Control of the Coordination Mode of the Salicylaldehyde Thiosemicarbazone Ligand. Syntheses, Structures, and Redox Properties of Ruthenium and Osmium Complexes Inorganic Chemistry. ,vol. 36, pp. 5645- 5647 ,(1997) , 10.1021/IC9705094
Sigurjón Norberg Ólafsson, Claus Flensburg, Peter Andersen, Lead(IV) complexes with phosphinoyldithioformates, R2P(O)CS2− (R = Ph or PhCH2). Syntheses and characterization. Crystal structures of [PPh4][S2CP(O)Ph2]·0.5H2O, [PbPh2{S2CP(O)Ph2}2] and [PbPh2Cl{S2CP(O)Ph2}] Journal of The Chemical Society-dalton Transactions. pp. 4360- 4368 ,(2000) , 10.1039/B006672I
Falguni Basuli, Shie-Ming Peng, Samaresh Bhattacharya, Unusual coordination mode of thiosemicarbazone ligands. A search for the origin. Inorganic Chemistry. ,vol. 39, pp. 1120- 1127 ,(2000) , 10.1021/IC991083R
Cheolki Paek, Sang Ook Kang, Jaejung Ko, Patrick J. Carroll, Thiosemicarbazone Complexes of Indium with New Modes of Coordination: X-ray Crystal Structure of {(Me2In)2[NC5H4CMeNNC(S)NC6H5]2}(InMe) Organometallics. ,vol. 16, pp. 4755- 4758 ,(1997) , 10.1021/OM970119P
Frank H. Allen, The Cambridge Structural Database: a quarter of a million crystal structures and rising Acta Crystallographica Section B-structural Science. ,vol. 58, pp. 380- 388 ,(2002) , 10.1107/S0108768102003890
Alfonso Castiñeiras, Elena Bermejo, Douglas X West, Ayman K El-Sawaf, John K Swearingen, Spectral and structural studies of metal complexes of 1-phenylglyoxal bis { {N (3) -diethylthiosemicarbazone} } Polyhedron. ,vol. 17, pp. 2751- 2757 ,(1998) , 10.1016/S0277-5387(98)00063-1
José S. Casas, Eduardo E. Castellano, Alejandro Macías, María C. Rodríguez-Argüelles, Agustín Sánchez, José Sordo, (p-Anisaldehyde thiosemicarbazonato)dimethylthallium(III): an unusual structure for a co-ordinated thiosemicarbazone Journal of The Chemical Society-dalton Transactions. pp. 353- 354 ,(1993) , 10.1039/DT9930000353
José. S. Casas, Eduardo E. Castellano, Javier Ellena, María S. García-Tasende, Agustín Sánchez, José Sordo, Ezequiel M. Vázquez-López, María J. Vidarte, Synthesis, Spectroscopic and Structural Aspects of Mono‐ and Diorganothallium(III) Complexes of 2, 6‐Diacetylpyridine Bis(thiosemicarbazone) (H2DAPTSC) — A New Coordination Mode of the HDAPTSC— Anion Zeitschrift für anorganische und allgemeine Chemie. ,vol. 629, pp. 261- 267 ,(2003) , 10.1002/ZAAC.200390042
José S Casas, Marı́a V Castaño, Marı́a C Cifuentes, Agustı́n Sánchez, José Sordo, Synthesis and structures of acetylferrocene thiosemicarbazones and their dimethylthallium(III) complexes, which have four- or five-membered chelate rings Polyhedron. ,vol. 21, pp. 1651- 1660 ,(2002) , 10.1016/S0277-5387(02)01035-5