Low temperature metallic conductivity in bis(tetrathiotetracene) triiodide, a new organic metal

作者: L.C. Isett , E.A. Perez-Albuerne

DOI: 10.1016/0038-1098(77)91368-0

关键词: Materials scienceTriiodideConductivityMetallic conductivityInorganic chemistryElectrical resistivity and conductivityAtmospheric temperature rangeMetal

摘要: Abstract The d.c. electrical conductivity of bis(tetrathiotetracene)triiodide,a new organic metal, has been measured for 3.3K⩽T⩽300K. room temperature is ∼ 1000 Ω-1 cm-1. exhibits a broad maximum about 3000 cm-1 in the range 40–80 K followed by gradual decrease with decreasing temperature. No sharp metal-insulator transition observed down to 3.3 K. at 4 100

参考文章(9)
A. N. Bloch, D. O. Cowan, K. Bechgaard, R. E. Pyle, R. H. Banks, T. O. Poehler, Low-Temperature Metallic Behavior and Resistance Minimum in a New Quasi One-Dimensional Organic Conductor Physical Review Letters. ,vol. 34, pp. 1561- 1564 ,(1975) , 10.1103/PHYSREVLETT.34.1561
R. P. Groff, A. Suna, R. E. Merrifield, Temperature Dependence of Conductivity of Tetrathiafulvalene-Tetracyanoquinodimethane (TTF-TCNQ) Single Crystals Physical Review Letters. ,vol. 33, pp. 418- 421 ,(1974) , 10.1103/PHYSREVLETT.33.418
F. Denoyer, F. Comès, A. F. Garito, A. J. Heeger, X-Ray-Diffuse-Scattering Evidence for a Phase Transition in Tetrathiafulvalene Tetracyanoquinodimethane (TTF-TCNQ). Physical Review Letters. ,vol. 35, pp. 755- 755 ,(1975) , 10.1103/PHYSREVLETT.35.445
David E. Schafer, Fred Wudl, Gordon A. Thomas, John P. Ferraris, Dwaine O. Cowan, Apparent giant conductivity peaks in an anisotropic medium: TTF-TCNQ Solid State Communications. ,vol. 14, pp. 347- 351 ,(1974) , 10.1016/0038-1098(74)90915-6
V. Hádek, Semiconductive Properties of the Iodine Complex of N,N′‐Diphenyl‐p‐phenylenediamine Journal of Chemical Physics. ,vol. 49, pp. 5202- 5203 ,(1968) , 10.1063/1.1670030
R. Comès, S. M. Shapiro, G. Shirane, A. F. Garito, A. J. Heeger, Neutron-Scattering Study of the 38- and 54-K Phase Transitions in Deuterated Tetrathiafulvalene- Tetracyanoquinodimethane (TTF-TCNQ) Physical Review Letters. ,vol. 35, pp. 1518- 1521 ,(1975) , 10.1103/PHYSREVLETT.35.1518
E. A. Perez‐Albuerne, H. Johnson, D. J. Trevoy, Highly Conducting Ion‐Radical Salts of Tetrathiotetracene The Journal of Chemical Physics. ,vol. 55, pp. 1547- 1554 ,(1971) , 10.1063/1.1676278