Synthesis of highly stable gold nanoparticles using conventional and geminal ionic liquids
作者： A. Safavi , S. Zeinali
DOI: 10.1016/J.COLSURFA.2010.04.002
关键词: Ionic liquid 、 Bromide 、 Inorganic chemistry 、 Nanoparticle 、 Dynamic light scattering 、 Colloidal gold 、 Materials science 、 Dodecane 、 Fourier transform infrared spectroscopy 、 Ionic bonding
摘要: Abstract Highly stable and hydrophilic ionic liquid-capped gold nanoparticles were synthesized by in situ reduction of HAuCl 4 with NaBH an aqueous medium. Two kinds liquids (ILs) used this work: namely, 1-dodecyl-3-methylimidazolium chloride [C 12 mim][Cl] a geminal-IL (GIL), 1,4-bis(methylimidazolium-1yl)dodecane bromide, two head groups. Prepared characterized UV–vis spectra, transmission electron microscopy (TEM), dynamic light scattering (DLS) analysis FTIR spectroscopy. To the best our knowledge is first report on using these types ILs nanoparticle synthesis. The results showed synthesis low polydispersed sizes about 10 nm. IL ([C mim][Cl]) capped for at least 8 months.
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sci-hub.se 参考文章(58)
Peter Wasserscheid, Thomas Welton, Ionic Liquids in Synthesis ,(2002)
Robin D Rogers, Kenneth R Seddon, Ionic Liquids--Solvents of the Future? Science. ,vol. 302, pp. 792- 793 ,(2003) , 10.1126/SCIENCE.1090313
William Dobbs, Jean-Moïse Suisse, Laurent Douce, Richard Welter, Electrodeposition of silver particles and gold nanoparticles from ionic liquid-crystal precursors. Angewandte Chemie. ,vol. 45, pp. 4179- 4182 ,(2006) , 10.1002/ANIE.200600929
A. Safavi, G. Absalan, F. Bamdad, Effect of gold nanoparticle as a novel nanocatalyst on luminol-hydrazine chemiluminescence system and its analytical application. Analytica Chimica Acta. ,vol. 610, pp. 243- 248 ,(2008) , 10.1016/J.ACA.2008.01.053
Jared L. Anderson, Jie Ding, Thomas Welton, Daniel W. Armstrong, Characterizing ionic liquids on the basis of multiple solvation interactions. Journal of the American Chemical Society. ,vol. 124, pp. 14247- 14254 ,(2002) , 10.1021/JA028156H
Karuvath Yoosaf, Binil Itty Ipe, Cherumuttathu H. Suresh, K. George Thomas, In Situ Synthesis of Metal Nanoparticles and Selective Naked-Eye Detection of Lead Ions from Aqueous Media Journal of Physical Chemistry C. ,vol. 111, pp. 12839- 12847 ,(2007) , 10.1021/JP073923Q
M. Jaschke, H.-J. Butt, H. E. Gaub, S. Manne, Surfactant Aggregates at a Metal Surface Langmuir. ,vol. 13, pp. 1381- 1384 ,(1997) , 10.1021/LA9607767
Yugang Sun, Younan Xia, Shape-Controlled Synthesis of Gold and Silver Nanoparticles Science. ,vol. 298, pp. 2176- 2179 ,(2002) , 10.1126/SCIENCE.1077229
A. Safavi, H. Abdollahi, N. Maleki, S. Zeinali, Interaction of anionic dyes and cationic surfactants with ionic liquid character joint international conference on information sciences. ,vol. 322, pp. 274- 280 ,(2008) , 10.1016/J.JCIS.2008.01.059
Daniel V. Leff, Lutz Brandt, James R. Heath, Synthesis and Characterization of Hydrophobic, Organically-Soluble Gold Nanocrystals Functionalized with Primary Amines Langmuir. ,vol. 12, pp. 4723- 4730 ,(1996) , 10.1021/LA960445U