Solvent effects on infrared frequencies—I. The complexing of acetone and cyclohexanone with p-cresol and other phenols
作者： K.B. Whetsel , R.E. Kagarise
DOI: 10.1016/S0371-1951(62)80140-4
关键词: Photochemistry 、 Chemistry 、 Solvent effects 、 Cyclohexanone 、 p-Cresol 、 Acetone 、 Cyclohexane 、 Stability constants of complexes 、 Ethanol 、 Phenols
摘要: Abstract The carbonyl stretching bands of acetone and cyclohexanone were studied in various mixtures p-cresol cyclohexane. results indicate that 1:1 1:2 ketone-p-cresol complexes are formed at concentrations less than 0·3 M even higher exist concentrations. Formation constants for the determined used to resolve observed into spectra individual complexes. More limited data obtained with other phenols ethanol also presented. emphasize effects specific interactions on frequencies these systems. They show complex nature solvent-induced frequency shifts illustrate advantages using mixed solvents study shifts.
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