Liquid phase hydrogenation of methyl levulinate over the mixture of supported ruthenium catalyst and zeolite in water
作者： Jayprakash M. Nadgeri , Norihito Hiyoshi , Aritomo Yamaguchi , Osamu Sato , Masayuki Shirai
DOI: 10.1016/J.APCATA.2013.10.059
关键词: Metal 、 Catalysis 、 Chemistry 、 Ruthenium 、 Methyl levulinate 、 Yield (chemistry) 、 Graphite 、 Inorganic chemistry 、 Ruthenium catalyst 、 Zeolite
摘要: Abstract Liquid-phase hydrogenation of methyl levulinate was studied over graphite-supported ruthenium (Ru/graphite), zeolite-supported ruthenium, and a mixture Ru/graphite zeolites in water at 343 K. The final γ-valerolactone yield the ZSM-5 showed highest activities between Ru/graphite, Ru/ZSM-5, several zeolites. Methyl hydrogenated to 4-hydroxyvalerate or directly supported metal sites converted acid sites. contained both highly dispersed particles number rather than those catalysts, which led yield.
sci-hub.se 参考文章(28)
Leo E Manzer, Catalytic synthesis of α-methylene-γ-valerolactone: a biomass-derived acrylic monomer Applied Catalysis A-general. ,vol. 272, pp. 249- 256 ,(2004) , 10.1016/J.APCATA.2004.05.048
D. R. Dodds, R. A. Gross, Chemicals from Biomass Science. ,vol. 318, pp. 1250- 1251 ,(2007) , 10.1126/SCIENCE.1146356
Peter McKendry, Energy production from biomass (Part 1): Overview of biomass. Bioresource Technology. ,vol. 83, pp. 37- 46 ,(2002) , 10.1016/S0960-8524(01)00118-3
Juan Carlos Serrano-Ruiz, Dong Wang, James A. Dumesic, Catalytic upgrading of levulinic acid to 5-nonanone Green Chemistry. ,vol. 12, pp. 574- 577 ,(2010) , 10.1039/B923907C
Pierre Gallezot, Conversion of biomass to selected chemical products Chemical Society Reviews. ,vol. 41, pp. 1538- 1558 ,(2012) , 10.1039/C1CS15147A
Xian-Long Du, Qing-Yuan Bi, Yong-Mei Liu, Yong Cao, He-Yong He, Kang-Nian Fan, Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran Green Chemistry. ,vol. 14, pp. 935- 939 ,(2012) , 10.1039/C2GC16599F
Pravin P. Upare, Jong-Min Lee, Dong Won Hwang, Shiva B. Halligudi, Young Kyu Hwang, Jong-San Chang, Selective hydrogenation of levulinic acid to γ-valerolactone over carbon-supported noble metal catalysts Journal of Industrial and Engineering Chemistry. ,vol. 17, pp. 287- 292 ,(2011) , 10.1016/J.JIEC.2011.02.025
J. Q. Bond, D. M. Alonso, D. Wang, R. M. West, J. A. Dumesic, Integrated catalytic conversion of γ-valerolactone to liquid alkenes for transportation fuels. Science. ,vol. 327, pp. 1110- 1114 ,(2010) , 10.1126/SCIENCE.1184362
Kai Yan, Todd Lafleur, Guosheng Wu, Jiayou Liao, Chen Ceng, Xianmei Xie, Highly selective production of value-added γ-valerolactone from biomass-derived levulinic acid using the robust Pd nanoparticles Applied Catalysis A-general. ,vol. 468, pp. 52- 58 ,(2013) , 10.1016/J.APCATA.2013.08.037
Zhi-pei Yan, Lu Lin, Shijie Liu, Synthesis of γ-Valerolactone by Hydrogenation of Biomass-derived Levulinic Acid over Ru/C Catalyst Energy & Fuels. ,vol. 23, pp. 3853- 3858 ,(2009) , 10.1021/EF900259H