Ionic Liquids as Porogens in the Synthesis of Molecularly Imprinted Polymers

作者: Katherine M , Clovia I , Michael C , Adam McCluskey

DOI: 10.5772/21725

关键词: Crosslinked polymersSolventMaterials scienceMolecularly imprinted polymerIonic liquidPolymerizationChemical engineeringModel systemPolymer

摘要: Although the information regarding room temperature ionic liquids (RTILs) as polymerisation solvents is extensive, there has been very little research published using RTILs for synthesis of crosslinked polymers in general (Cooper 2004; Pavlova 2006) and molecularly imprinted (MIPs) particular (Booker et al 2006, 2007; Wang 2008; He 2008). Herein we examine a model system, cocaine, will review properties performance prepared volatile organic compounds (VOCs) with those RTILs, experimental parameters such temperature, solvent volume, rebinding conditions template-RTIL combination, which may have role to play these systems.

参考文章(23)
Börje Sellergren, Molecularly imprinted polymers : man-made mimics of antibodies and their applications in analytical chemistry Published in <b>2001</b> in Amsterdam New York by Elsevier. ,(2001)
Anna M. Crabtree, James F. O'Brien, Excess viscosities of binary mixtures of chloroform and alcohols Journal of Chemical & Engineering Data. ,vol. 36, pp. 140- 142 ,(1991) , 10.1021/JE00002A003
Elena V. Piletska, António R. Guerreiro, Michael J. Whitcombe, Sergey A. Piletsky, Influence of the Polymerization Conditions on the Performance of Molecularly Imprinted Polymers Macromolecules. ,vol. 42, pp. 4921- 4928 ,(2009) , 10.1021/MA900432Z
Katherine Booker, Michael C. Bowyer, Chris J. Lennard, Clovia I. Holdsworth, Adam McCluskey, Molecularly imprinted polymers and room temperature ionic liquids : Impact of template on polymer morphology Australian Journal of Chemistry. ,vol. 60, pp. 51- 56 ,(2007) , 10.1071/CH06284
Liang Cheng, Yumei Zhang, Tingting Zhao, Huaping Wang, Free Radical Polymerization of Acrylonitrile in Green Ionic Liquids Macromolecular Symposia. ,vol. 216, pp. 9- 16 ,(2004) , 10.1002/MASY.200451202
Adam McCluskey, Clovia I. Holdsworth, Michael C. Bowyer, Molecularly imprinted polymers (MIPs): sensing, an explosive new opportunity? Organic and Biomolecular Chemistry. ,vol. 5, pp. 3233- 3244 ,(2007) , 10.1039/B708660A
Natalia Pérez-Moral, Andrew G. Mayes, Noncovalent imprinting in the shell of core-shell nanoparticles. Langmuir. ,vol. 20, pp. 3775- 3779 ,(2004) , 10.1021/LA0356755