Controlled mechanical fracture for fabricating microchannels with various size gradients

作者: Hong-Nam Kim , Sung-Hoon Lee , Kahp-Yang Suh

DOI: 10.1039/C0LC00277A

关键词: Structural engineeringAnisotropyComposite materialRadiusFracture (geology)Masking (art)WavelengthMaterials scienceLayer (electronics)PolydimethylsiloxaneSlab

摘要: We present a simple method to generate cracks with controllable size (depth and width) space gradients using deep surface oxidation anisotropic mechanical stretching. To thick layer (<∼7 µm), polydimethylsiloxane (PDMS) slab of uniform or varying thickness was exposed UV/ozone for less than 30 min in the UV-C wavelength including wavelengths 185 254 nm. Subsequently, PDMS wrapped on cylindrical support (radius: 11 mm) apply bending strain (<21%), resulting equally separated, over large area. By modulating initial depth applied stress, sizes spaces were formed single slab. Furthermore, multiple, sequential generated by increasing step-wise fashion multi-directional applying an orientation angle. Finally, space-varying between two adjacent channels interconnected format selective masking irreversible bonding.

参考文章(43)
L. Rey, N. Poisson, A. Maazouz, H. Sautereau, Enhancement of crack propagation resistance in epoxy resins by introducing poly(dimethylsiloxane) particles Journal of Materials Science. ,vol. 34, pp. 1775- 1781 ,(1999) , 10.1023/A:1004555008043
J.L. Beuth, N.W. Klingbeil, Cracking of thin films bonded to elastic-plastic substrates Journal of The Mechanics and Physics of Solids. ,vol. 44, pp. 1411- 1428 ,(1996) , 10.1016/0022-5096(96)00042-7
H. Hillborg, J.F. Ankner, U.W. Gedde, G.D. Smith, H.K. Yasuda, K. Wikström, Crosslinked polydimethylsiloxane exposed to oxygen plasma studied by neutron reflectometry and other surface specific techniques Polymer. ,vol. 41, pp. 6851- 6863 ,(2000) , 10.1016/S0032-3861(00)00039-2
C. Chen, D. Hirdes, A. Folch, Gray-scale photolithography using microfluidic photomasks Proceedings of the National Academy of Sciences of the United States of America. ,vol. 100, pp. 1499- 1504 ,(2003) , 10.1073/PNAS.0435755100
Christopher M. Stafford, Bryan D. Vogt, Christopher Harrison, Duangrut Julthongpiput, Rui Huang, Elastic Moduli of Ultrathin Amorphous Polymer Films Macromolecules. ,vol. 39, pp. 5095- 5099 ,(2006) , 10.1021/MA060790I
Limin Gao, Erik T. Thostenson, Zuoguang Zhang, Tsu-Wei Chou, Sensing of Damage Mechanisms in Fiber-Reinforced Composites under Cyclic Loading using Carbon Nanotubes Advanced Functional Materials. ,vol. 19, pp. 123- 130 ,(2009) , 10.1002/ADFM.200800865
Dong Choon Hyun, Geon Dae Moon, Eun Chul Cho, Unyong Jeong, Repeated Transfer of Colloidal Patterns by Using Reversible Buckling Process Advanced Functional Materials. ,vol. 19, pp. 2155- 2162 ,(2009) , 10.1002/ADFM.200900202
Dongeun Huh, K. L. Mills, Xiaoyue Zhu, Mark A. Burns, M. D. Thouless, Shuichi Takayama, Tunable elastomeric nanochannels for nanofluidic manipulation Nature Materials. ,vol. 6, pp. 424- 428 ,(2008) , 10.1038/NMAT1907
Moon Kyu Kwak, Hoon-Eui Jeong, Tae-il Kim, Hyunsik Yoon, Kahp Y. Suh, Bio-inspired slanted polymer nanohairs for anisotropic wetting and directional dry adhesion Soft Matter. ,vol. 6, pp. 1849- 1857 ,(2010) , 10.1039/B924056J