The three transglycosylation reactions catalyzed by cyclodextrin glycosyltransferase from Bacillus circulans (strain 251) proceed via different kinetic mechanisms

作者: Bart A. van der Veen , Gert-Jan W. M. van Alebeek , Joost C. M. Uitdehaag , Bauke W. Dijkstra , Lubbert Dijkhuizen

DOI: 10.1046/J.1432-1327.2000.01031.X

关键词: CyclodextrinCyclodextrin glycosyltransferaseCovalent bondDisproportionationChemistryCoupling reactionTernary complexSubstrate (chemistry)Reaction rateStereochemistry

摘要: … or starch and subsequent formation of a cyclodextrin) is a single‐… Coupling (cleavage of an α‐glycosidic bond in a cyclodextrin … oligosaccharides instead of cyclodextrins thus appears …

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