作者: René Kalio , Peter Lönnecke , Evamarie Hey-Hawkins
DOI: 10.1016/J.JORGANCHEM.2007.10.060
关键词: Phosphonium 、 Chemistry 、 Yield (chemistry) 、 Coordination complex 、 Infrared spectroscopy 、 Na(2)S(2)O(5) 、 Medicinal chemistry 、 Stereochemistry 、 Phosphonium salt 、 Ligand 、 Crystal structure 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Organic chemistry 、 Materials Chemistry 、 Biochemistry
摘要: The new ferrocenylmethylphosphines PH(CH 2 Fc) ( 1 ) [Fc = Fe(η 5 -C H )(η 4 )] and P(CH 3 the phosphonium salt [P(CH (CH OH)]I were synthesised from OH) [FcCH NMe ]I. Fc)(CH ]Cl was obtained , CH O HCl. phosphines salts fully characterised by NMR IR spectroscopy MS. [Mo(CO) 6 ] reacts with to give {PH(CH }] in high yield, but attempts employ as a ligand failed. reaction of [PH(CH ]I (obtained situ Na S [WI (CO) (NCMe) gave complex OH)][WI ][WI 7 ), respectively. 8 synthesized PH Fc Crystal structures for – .