Thermodynamic Study of Solar Thermochemical Methane Steam Reforming with Alternating H2 and CO2 Permeation Membranes Reactors
作者： Hongsheng Wang , Yong Hao
DOI: 10.1016/J.EGYPRO.2017.03.570
关键词: Hydrogen production 、 Chemistry 、 Solar fuel 、 Hydrogen economy 、 Methane 、 Steam reforming 、 Chemical engineering 、 Solar energy 、 Thermodynamics 、 Methane reformer 、 Carbon dioxide reforming
摘要: Abstract Hydrogen production by way of methane steam reforming based on solar energy is a promising means harvesting and storage. In this work, concept solar-driven thermochemical hydrogen derivation alternating carbon dioxide permeation membranes proposed, which capable driving reaction towards virtual completion isothermally in the temperature range 400-700 °C. Thermodynamic analysis performed one-dimensional model reactor consisting alternate H2 CO2 membranes. At 400 °C, both conversion rates water can reach 99.9%, while solar-to-fuel efficiency 61.7% when solar-to-electricity 15%. Major advantages approach include high efficiency, isothermal continuous operation low theoretical penalties for separation. This study brings new insights into efficient low/mid-temperature fuel production.
sci-hub.se 参考文章(13)
Zee Ying Yeo, Thiam Leng Chew, Peng Wei Zhu, Abdul Rahman Mohamed, Siang-Piao Chai, Synthesis and performance of microporous inorganic membranes for CO2 separation: a review Journal of Porous Materials. ,vol. 20, pp. 1457- 1475 ,(2013) , 10.1007/S10934-013-9732-0
Gioele Di Marcoberardino, Francesco Sosio, Giampaolo Manzolini, Stefano Campanari, Fixed bed membrane reactor for hydrogen production from steam methane reforming: Experimental and modeling approach International Journal of Hydrogen Energy. ,vol. 40, pp. 7559- 7567 ,(2015) , 10.1016/J.IJHYDENE.2014.11.045
S. J. Chung, J. H. Park, D. Li, J.-I. Ida, I. Kumakiri, Jerry Y. S. Lin, Dual-Phase Metal−Carbonate Membrane for High-Temperature Carbon Dioxide Separation Industrial & Engineering Chemistry Research. ,vol. 44, pp. 7999- 8006 ,(2005) , 10.1021/IE0503141
Toshiyuki Mori, Yarong Wang, John Drennan, Graeme Auchterlonie, Ji-Guang Li, Takayasu Ikegami, Influence of particle morphology on nanostructural feature and conducting property in Sm-doped CeO2 sintered body Solid State Ionics. ,vol. 175, pp. 641- 649 ,(2004) , 10.1016/J.SSI.2004.09.046
Syed A.M. Said, David S.A. Simakov, Esmail M.A. Mokheimer, Mohamed A. Habib, Shakeel Ahmed, Mohammed Waseeuddin, Yuriy Román-Leshkov, Computational fluid dynamics study of hydrogen generation by low temperature methane reforming in a membrane reactor International Journal of Hydrogen Energy. ,vol. 40, pp. 3158- 3169 ,(2015) , 10.1016/J.IJHYDENE.2015.01.024
Philipp Good, Gianluca Ambrosetti, Andrea Pedretti, Aldo Steinfeld, An array of coiled absorber tubes for solar trough concentrators operating with air at 600 °C and above Solar Energy. ,vol. 111, pp. 378- 395 ,(2015) , 10.1016/J.SOLENER.2014.09.016
Xiang Wu, Cheng Wu, Sufang Wu, Dual-enhanced steam methane reforming by membrane separation of H2 and reactive sorption of CO2 Chemical Engineering Research & Design. ,vol. 96, pp. 150- 157 ,(2015) , 10.1016/J.CHERD.2015.02.010
Shin-Kun Ryi, Jong-Soo Park, Dong-Kook Kim, Tae-Hwan Kim, Sung-Hyun Kim, Methane steam reforming with a novel catalytic nickel membrane for effective hydrogen production Journal of Membrane Science. ,vol. 339, pp. 189- 194 ,(2009) , 10.1016/J.MEMSCI.2009.04.047
Leonardo Roses, Fausto Gallucci, Giampaolo Manzolini, Martin van Sint Annaland, Experimental study of steam methane reforming in a Pd-based fluidized bed membrane reactor Chemical Engineering Journal. ,vol. 222, pp. 307- 320 ,(2013) , 10.1016/J.CEJ.2013.02.069
Roman Bader, Andrea Pedretti, Maurizio Barbato, Aldo Steinfeld, An air-based corrugated cavity-receiver for solar parabolic trough concentrators Applied Energy. ,vol. 138, pp. 337- 345 ,(2015) , 10.1016/J.APENERGY.2014.10.050