Iodine-catalyzed ammoxidation of methyl arenes

作者: Songjin Guo , Gen Wan , Song Sun , Yan Jiang , Jin-Tao Yu

DOI: 10.1039/C5CC01024A

关键词: AmmoxidationArylChemistryCyanationCatalysisOrganic chemistryIodine

摘要: The development of organic transformation using cheap and readily available substrates under mild conditions will be pivotal for green sustainable synthetic chemistry. Concerning our continued interest in the cyanation reaction, a metal-free direct ammoxidation methyl arenes leading to nitriles was established conditions. A series aryl methanes especially heteroaryl (30 examples) were applicable moderate good yields with functionality tolerance.

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