High-performance carbon monoxide gas sensor based on palladium/tin oxide/porous graphitic carbon nitride nanocomposite

作者: S. Absalan , Sh. Nasresfahani , M.H. Sheikhi

DOI: 10.1016/J.JALLCOM.2019.04.187

关键词: Tin oxideNanoparticleNanocompositeGraphitic carbon nitrideMaterials sciencePalladiumFourier transform infrared spectroscopyCarbon monoxideChemical engineeringSpectroscopy

摘要: Abstract The palladium (Pd)/tin oxide (SnO2)/porous graphitic carbon nitride (g-C3N4) nanocomposites with different Pd and g-C3N4 contents were synthesized by a facile hydrothermal route their applications as efficient monoxide (CO) gas sensors investigated. These characterized in detail X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), micrograph techniques (FESEM TEM), energy dispersive (EDS), order to evaluate structural morphological properties. On the basis of FESEM TEM analysis, two-dimensional porous nanosheets provided large surface area suitable for growth SnO2 nanoparticles formation heterogeneous nanocomposite. Among weight ratios components Pd/SnO2/g-C3N4 nanocomposites, 5%Pd/SnO2/5%g-C3N4 exhibited excellent CO sensing characteristics such high response, short response/recovery times, good selectivity stability at lower operating temperature 125 °C. outstanding performance these could be attributed g-C3N4, strong spillover effect well g-C3N4/SnO2 heterojunction.

参考文章(67)
Qingji Wang, Chen Wang, Hongbin Sun, Peng Sun, Yongzhi Wang, Jun Lin, Geyu Lu, Microwave assisted synthesis of hierarchical Pd/SnO2 nanostructures for CO gas sensor Sensors and Actuators B: Chemical. ,vol. 222, pp. 257- 263 ,(2016) , 10.1016/J.SNB.2015.07.115
Clive Mumford, Phillip Carson, Hazardous chemicals handbook ,(1994)
Ahmet Gümüş, ABDULMECİT Türüt, N Yalcin, Temperature dependent barrier characteristics of CrNiCo alloy Schottky contacts on n-type molecular-beam epitaxy GaAs Journal of Applied Physics. ,vol. 91, pp. 245- 250 ,(2002) , 10.1063/1.1424054
Xu Liu, Nan Chen, Bingqian Han, Xuechun Xiao, Gang Chen, Igor Djerdj, Yude Wang, Nanoparticle cluster gas sensor: Pt activated SnO2 nanoparticles for NH3 detection with ultrahigh sensitivity. Nanoscale. ,vol. 7, pp. 14872- 14880 ,(2015) , 10.1039/C5NR03585F
Yang Liu, Shiting Yao, Qiuyue Yang, Peng Sun, Yuan Gao, Xishuang Liang, Fengmin Liu, Geyu Lu, Highly sensitive and humidity-independent ethanol sensors based on In2O3 nanoflower/SnO2 nanoparticle composites RSC Advances. ,vol. 5, pp. 52252- 52258 ,(2015) , 10.1039/C5RA07213A
Mauro Epifani, Jordi Arbiol, Eva Pellicer, Elisabetta Comini, Pietro Siciliano, Guido Faglia, Joan R. Morante, Synthesis and Gas-Sensing Properties of Pd-Doped SnO2 Nanocrystals. A Case Study of a General Methodology for Doping Metal Oxide Nanocrystals Crystal Growth & Design. ,vol. 8, pp. 1774- 1778 ,(2008) , 10.1021/CG700970D
Yipeng Zang, Liping Li, Xiaoguo Li, Rui Lin, Guangshe Li, Synergistic collaboration of g-C3N4/SnO2 composites for enhanced visible-light photocatalytic activity Chemical Engineering Journal. ,vol. 246, pp. 277- 286 ,(2014) , 10.1016/J.CEJ.2014.02.068
He Zhang, Wen Zeng, Jinghua Hao, Yanqiong Li, Bin Miao, Hydrothermal synthesis of flower-like SnO2 architectures with superior gas sensing properties Materials Letters. ,vol. 145, pp. 133- 136 ,(2015) , 10.1016/J.MATLET.2015.01.098
Ireneusz Kocemba, Jacek Rynkowski, The influence of catalytic activity on the response of Pt/SnO2 gas sensors to carbon monoxide and hydrogen Sensors and Actuators B: Chemical. ,vol. 155, pp. 659- 666 ,(2011) , 10.1016/J.SNB.2011.01.026
Qing-Fang Deng, Lei Liu, Xiu-Zhen Lin, Gaohui Du, Yuping Liu, Zhong-Yong Yuan, Synthesis and CO2 capture properties of mesoporous carbon nitride materials Chemical Engineering Journal. ,vol. 203, pp. 63- 70 ,(2012) , 10.1016/J.CEJ.2012.06.124