CO2 reforming of CH4 over nanocrystalline zirconia-supported nickel catalysts
作者： M. Rezaei , S.M. Alavi , S. Sahebdelfar , Peng Bai , Xinmei Liu
DOI: 10.1016/J.APCATB.2007.08.004
关键词: Syngas 、 Mesoporous material 、 Nickel 、 Cubic zirconia 、 Calcination 、 Carbon dioxide reforming 、 Materials science 、 Catalyst support 、 Chemical engineering 、 Inorganic chemistry 、 Catalysis
摘要: Abstract Mesoporous nanocrystalline zirconia with high-surface area and pure tetragonal crystalline phase has been prepared by the surfactant-assisted route, using Pluronic P123 block copolymer surfactant. The synthesized showed a surface of 174 m2 g−1 after calcination at 700 °C for 4 h. was employed as support nickel catalysts in dry reforming reaction. It found that these possessed mesoporous structure even area. activity results indicated catalyst stable syngas production decrease about 4% methane conversion 50 h Addition promoters (CeO2, La2O3 K2O) to improved both stability catalyst, without any
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