The thermal decomposition of polyvinylchloride—iii.: An investigation of discolouration
作者： W.C. Geddes
DOI: 10.1016/0014-3057(67)90059-6
关键词: Absorption spectroscopy 、 Polymer chemistry 、 Inorganic chemistry 、 Peroxide 、 Sequence (biology) 、 Spectral line 、 Materials science 、 Thermal decomposition 、 Polyene 、 Polymer
摘要: Abstract Absorption spectra of thermally degraded PVC films are recorded for a number polymer samples submitted to various dehydrochlorination conditions and in the presence stabilizers. Correlations drawn between colour dehydrochlorination; also discussed qualitatively with special reference stabilization. The average polyene sequence length is calculated using an ozonization technique compared values derived from peroxide data absorption spectra.
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sci-hub.se 参考文章(28)
W.C. Geddes, The thermal decomposition of polyvinylchloride—ii.: Peroxide structures as initiators for dehydrochlorination European Polymer Journal. ,vol. 3, pp. 733- 745 ,(1967) , 10.1016/0014-3057(67)90058-4
Chr. P. Pinazzi, H. Gueniffey, Halogénation et déhydrohalogénation des cis-1,4 polyisoprènes et polyènes analogues† Macromolecular Chemistry and Physics. ,vol. 93, pp. 109- 125 ,(1966) , 10.1002/MACP.1966.020930107
Alain Guyot, Jean-Paul Benevise, Yves Trambouze, Sur la déagradation thermique du chlorure de polyvinyle. II. Etudes cinéatiques sous atmosphéare inerte Journal of Applied Polymer Science. ,vol. 6, pp. 103- 110 ,(1962) , 10.1002/APP.1962.070061912
Akio Nakajima, Humiyuki Hamada, Seiichi Hayashi, Structure and some physical properties of polyvinyl chloride polymerized at different temperatures Macromolecular Chemistry and Physics. ,vol. 95, pp. 40- 51 ,(1966) , 10.1002/MACP.1966.020950103
Saul B. Needleman, M. C. Chang Kuo, Diels-Alder Syntheses with Heteroatomic Compounds. Chemical Reviews. ,vol. 62, pp. 405- 431 ,(1962) , 10.1021/CR60219A002
P. Nayler, M. C. Whiting, Researches on polyenes. Part III. The synthesis and light absorption of dimethylpolyenes Journal of The Chemical Society (resumed). pp. 3037- 3047 ,(1955) , 10.1039/JR9550003037
D. E. Winkler, Mechanism of polyvinyl chloride degradation and stabilization Journal of Polymer Science. ,vol. 35, pp. 3- 16 ,(1959) , 10.1002/POL.1959.1203512802
Charles W. Spangler, G. Forrest Woods, cis-1,3,5-Hexatriene and Chloro- and Methyl-1,3,5-hexatrienes Journal of Organic Chemistry. ,vol. 30, pp. 2218- 2222 ,(1965) , 10.1021/JO01018A024
W.I. Bengough, I.K. Varma, The thermal degradation of polyvinylchloride in solution—IV. Changes in absorption spectra during degradation European Polymer Journal. ,vol. 2, pp. 61- 77 ,(1966) , 10.1016/0014-3057(66)90061-9
G. Forrest Woods, Louis H. Schwartzman, 1,3,5-Hexatriene. Journal of the American Chemical Society. ,vol. 70, pp. 3394- 3396 ,(1948) , 10.1021/JA01190A052