Carbon-supported Pd–Ir catalyst as anodic catalyst in direct formic acid fuel cell

作者: Xin Wang , Yawen Tang , Ying Gao , Tianhong Lu

DOI: 10.1016/J.JPOWSOUR.2007.10.011

关键词: PlatinumFormic acid fuel cellElectrocatalystFormic acidPalladiumInorganic chemistryCatalysisMethanolChemistryIridium

摘要: Abstract It was reported for the first time that electrocatalytic activity of Carbon-supported Pd–Ir (Pd–Ir/C) catalyst with suitable atomic ratio Pd and Ir oxidation formic acid in direct fuel cell (DFAFC) is better than (Pd/C) catalyst, although has no acid. The potential anodic peak at Pd–Ir/C electrode Ir = 5:1 50 mV more negative current density 13% higher Pd/C electrode. This attributed to can promote through pathway because decrease adsorption strength CO on Pd. However, when content too high would be decreased

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