Chapter 10 – Conversion

作者: Norbert Berkowitz

DOI: 10.1016/B978-012091090-8/50010-1

关键词: Coal rankHydrocarbonWaste managementSyngasEnvironmental scienceSolid fractionLiquefactionMolecular degradation

摘要: Publisher Summary This chapter highlights conversion, including gasification and liquefaction, of fossil hydrocarbons. The term “conversion” for hydrocarbons is used to denote that transforms a solid or liquid substance into gaseous fuels liquefaction converts semisolid heavy hydrocarbon lighter “synthetic” oil by controlled molecular degradation. Both technologies attest the inherent versatility potential interchangeability Gasification thermally cracks an H-rich correspondingly C-enriched fraction thereby yields gas as by-product. It entire organic feed useful therefore deployed generation syngas fuel gases with varying heat contents. Specific information about chemistry kinetics still fragmentary and, at times, contradictory. Thus, disagreeing one study, from which it was concluded asphahenes plus fell systematically increasing coal rank another found grossly divergent dependencies yields, apparently because different regional metamorphic histories consequent disparate rank/reactivity relationships.

参考文章(19)
W. G. WILLSON, L. J. SEALOCK, F. C. HOODMAKER, R. W. HOFFMAN, D. L. STINSON, J. L. COX, Alkali carbonate and nickel catalysis of coal-steam gasification. [Use of K carbonate and/or Ni; 20 wt. % K carbonate produces optimum gasification results] Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States). ,vol. 131, ,(1974) , 10.1021/BA-1974-0131.CH012
N. GARDNER, E. SAMUELS, K. WILKS, Catalyzed hydrogasification of coal chars. [Thermobalance (0-1000/sup 0/, 0-1000 psi); catalyst (K bicarbonate, K carbonate, and Zn chloride)] Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States). ,vol. 131, ,(1973) , 10.1021/BA-1974-0131.CH013
Herbert Kölbel, Kshitindra Kumar Bhattacharyya, Synthese hochschmelzender Paraffine an Ruthenium-Kontakten Justus Liebigs Annalen der Chemie. ,vol. 618, pp. 67- 71 ,(1958) , 10.1002/JLAC.19586180109
Franz Fischer, Hans Tropsch, Über die Synthese höherer Glieder der aliphatischen Reihe aus Kohlenoxyd European Journal of Inorganic Chemistry. ,vol. 56, pp. 2428- 2443 ,(1923) , 10.1002/CBER.19230561119
Kouichi Miura, Kenji Hashimoto, Peter L. Silveston, Factors affecting the reactivity of coal chars during gasification, and indices representing reactivity Fuel. ,vol. 68, pp. 1461- 1475 ,(1989) , 10.1016/0016-2361(89)90046-X
Concepción Salinas-Martínez de Lecea, Mariano Almela-Alarcón, Angel Linares-Solano, Calcium-catalysed carbon gasification in CO2 and steam Fuel. ,vol. 69, pp. 21- 27 ,(1990) , 10.1016/0016-2361(90)90253-M
F. G. Boehm, R. D. Caron, D. K. Banerjee, Coprocessing technology development in Canada Energy & Fuels. ,vol. 3, pp. 116- 119 ,(1989) , 10.1021/EF00014A001
M. D. Schlesinger, J. J. Demeter, Murray Greyson, Catalyst for Producing Methane from Hydrogen and Carbon Monoxide Industrial & Engineering Chemistry. ,vol. 48, pp. 68- 70 ,(1956) , 10.1021/IE50553A022