Total angular momentum conservation in statistical unimolecular theory should be represented in energy space
作者： Kjell Rynefors , Per Anders Elofson
DOI: 10.1016/0009-2614(81)80360-0
关键词: Rotational transition 、 Angular momentum operator 、 Total angular momentum quantum number 、 Statistical physics 、 Specific relative angular momentum 、 Angular momentum 、 Wigner–Eckart theorem 、 Physics 、 Angular momentum coupling 、 Classical mechanics
摘要: Abstract A representation of total angular momentum conservation in energy space is described. Several advantages such a are discussed, primarily connection with statistical unimolecular theory, experimental branching ratios and product distributions. Specific examples given for the systems K + CsF O I2.
harvard.edu
elsevier.com
sci-hub.se 参考文章(12)
M. Tamir, R.D. Levine, Translational energy requirements and disposal in molecular collisions: II. Branching ratios and products state distributions for the exchange reactions of alkali atoms with alkali halides principles and practice of constraint programming. ,vol. 18, pp. 125- 144 ,(1976) , 10.1016/0301-0104(76)87041-3
S.A. Safron, N.D. Weinstein, D.R. Herschbach, J.C. Tully, Transition state theory for collision complexes: product translational energy distributions Chemical Physics Letters. ,vol. 12, pp. 564- 568 ,(1972) , 10.1016/0009-2614(72)80009-5
S. Stolte, A. E. Proctor, W. M. Pope, R. B. Bernstein, Rotational energy effect upon the branching fraction for reactive decay of the CsF+K collision complex The Journal of Chemical Physics. ,vol. 66, pp. 3468- 3481 ,(1977) , 10.1063/1.434433
R. A. Marcus, On the theory of energy distributions of products of molecular beam reactions involving transient complexes The Journal of Chemical Physics. ,vol. 62, pp. 1372- 1384 ,(1975) , 10.1063/1.430649
Rakhal C. Bhattacharjee, Wendell Forst, A Modified statistical theory of collisional energy transfer in thermal reactions Chemical Physics. ,vol. 30, pp. 217- 241 ,(1978) , 10.1016/0301-0104(78)85121-0
Leif Holmlid, Kjell Rynefors, Monte Carlo simulation of RRKM unimolecular decomposition in molecular beam experiments. I. Basic considerations and calculational procedure principles and practice of constraint programming. ,vol. 60, pp. 393- 404 ,(1981) , 10.1016/0301-0104(81)80175-9
Arunava Gupta, David S. Perry, Richard N. Zare, Effect of reagent translation on the dynamics of the exothermic reaction Ba+HF Journal of Chemical Physics. ,vol. 72, pp. 6237- 6249 ,(1980) , 10.1063/1.439082
S. Stolte, A. E. Proctor, R. B. Bernstein, Translational energy dependence of the branching fraction and cross sections for the decay of collision complexes: K+CsF, RbF Journal of Chemical Physics. ,vol. 65, pp. 4990- 5008 ,(1976) , 10.1063/1.432933
Alan Carrington, Paul N. Dyer, Donald H. Levy, Gas‐Phase Electron Resonance Spectra of BrO and IO The Journal of Chemical Physics. ,vol. 52, pp. 309- 314 ,(1970) , 10.1063/1.1672684
A. B. Lees, G. H. Kwei, Molecular beam kinetics: The reactions of Li atoms with alkali halide molecules The Journal of Chemical Physics. ,vol. 58, pp. 1710- 1721 ,(1973) , 10.1063/1.1679416