Synthesis of Optically Active γ- and δ-Lactones by Microbiological Reduction

作者: G. TUYNENBURG MUYS , B. VAN DER VEN , A. P. DE JONGE

DOI: 10.1038/194995B0

关键词: Reduction (complexity)ChemistryYield (chemistry)Nuclear chemistryOptically active

摘要: MICROBIOLOGICAL reductions of α-keto-groups have been reported by Neuberg et al.1. Lemieux and Giquere2 carried out β-keto-caproic β-keto-caprylic acids. Microbiological γ- δ-keto-acids to yield optically active lactones so far not described in the literature.

参考文章(1)
R. U. Lemieux, Jacques Giguere, BIOCHEMISTRY OF THE USTILAGINALES: IV. THE CONFIGURATIONS OF SOME β–HYDROXYACIDS AND THE BIOREDUCTION OF β–KETOACIDS Canadian Journal of Chemistry. ,vol. 29, pp. 678- 690 ,(1951) , 10.1139/V51-076