Stoichiometry and kinetics of low-temperature oxidation of di-.mu.-chlorobis(N,N,N',N'-tetraethylethylenediamine)dicopper by dioxygen in methylene chloride and properties of the peroxocopper products

作者: Geoffrey Davies , Mohamed A. El-Sayed , Maher Henary

DOI: 10.1021/IC00267A011

关键词: OxygenReaction intermediatePolymer chemistryOxygeneMethyleneKineticsChlorideStoichiometryChemistryInorganic chemistryDiamine

摘要: Oxydation donnant le complexe LCu(Cl,O,Cl)CuL qui serait produit d'oxydation primaire aux temperatures >−26°C, existence de 2 formes d'un peroxo Cu, tetranucleaire et a valence mixte

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