Probing Solvation Dynamics around Aromatic and Biological Molecules at the Single-Molecular Level
作者： Otto Dopfer , Masaaki Fujii
DOI: 10.1021/ACS.CHEMREV.5B00610
关键词: Solvation shell 、 Reaction intermediate 、 Molecule 、 Chemistry 、 Photoionization 、 Implicit solvation 、 Photodissociation 、 Computational chemistry 、 Solvation 、 Intermolecular force
摘要: Solvation processes play a crucial role in chemical reactions and biomolecular recognition phenomena. Although solvation dynamics of interfacial or biological water has been studied extensively aqueous solution, the results are generally averaged over several layers motion individual solvent molecules is difficult to capture. This review describes development application new experimental approach, namely, picosecond time-resolved pump–probe infrared spectroscopy size- isomer-selected aromatic clusters, which for first time single molecule can be followed real time. The intermolecular isomerization reaction triggered by resonant photoionization (pump), photodissociation (probe) at variable delay generates spectroscopic signature salient properties reaction, including rates, yields, pathways, branching ratios competing reactions, existence intermediates, occurrence back ...
acs.org
cheric.org参考文章(217)
Jennifer C. Ma, Dennis A. Dougherty, The Cationminus signpi Interaction. Chemical Reviews. ,vol. 97, pp. 1303- 1324 ,(1997) , 10.1021/CR9603744
M. Okumura, L. I. Yeh, J. D. Myers, Yuan T. Lee, Infrared spectra of the solvated hydronium ion: Vibrational predissociation spectroscopy of mass-selected H3O+.cntdot.(H2O)n.cntdot.(H2)m The Journal of Physical Chemistry. ,vol. 94, pp. 3416- 3427 ,(1990) , 10.1021/J100372A014
Gas-Phase IR Spectroscopy and Structure of Biological Molecules Topics in Current Chemistry. ,(2015) , 10.1007/978-3-319-19204-8
M. Gerhards, A. Jansen, C. Unterberg, A. Gerlach, Structures and rearrangement reactions of 4-aminophenol(H2O)1+ and 3-aminophenol(H2O)1+ clusters. Journal of Chemical Physics. ,vol. 123, pp. 074320- 074320 ,(2005) , 10.1063/1.2008255
Friedrich Schotte, Manho Lim, Timothy A Jackson, Aleksandr V Smirnov, Jayashree Soman, John S Olson, George N Phillips Jr, Michael Wulff, Philip A Anfinrud, Watching a Protein as it Functions with 150-ps Time-Resolved X-ray Crystallography Science. ,vol. 300, pp. 1944- 1947 ,(2003) , 10.1126/SCIENCE.1078797
Otto Dopfer, Doris Roth, Rouslan V. Olkhov, John P. Maier, Infrared spectrum and ab initio calculations of the CH3CNH+-H2 ionic complex Journal of Chemical Physics. ,vol. 110, pp. 11911- 11917 ,(1999) , 10.1063/1.479176
O. Dopfer, V. Engel, Infrared spectrum and predissociation dynamics of H[sub 2]O[sup +]–Ar The Journal of Chemical Physics. ,vol. 121, pp. 12345- 12352 ,(2004) , 10.1063/1.1825998
Bertil Halle, Vladimir P. Denisov, Bengt-Harald Jonsson, Hydration of denatured and molten globule proteins. Nature Structural & Molecular Biology. ,vol. 6, pp. 253- 260 ,(1999) , 10.1038/6692
Dongping Zhong, Hydration Dynamics and Coupled Water–Protein Fluctuations Probed by Intrinsic Tryptophan John Wiley & Sons, Inc.. pp. 83- 149 ,(2009) , 10.1002/9780470508602.CH3
Xin Tong, Antonio Armentano, Mikko Riese, Med BenYezzar, Simon M. Pimblott, Klaus Müller-Dethlefs, Shun-ichi Ishiuchi, Makoto Sakai, Akihiro Takeda, Masaaki Fujii, Otto Dopfer, Dissociation energetics of the phenol+⋯Ar2 cluster ion: The role of π→H isomerization Journal of Chemical Physics. ,vol. 133, pp. 154308- 154308 ,(2010) , 10.1063/1.3482733