ZrCl4 as catalyst for olefins and styrene polymerization: Effect of ethereal donors on the activity and stereospecificity

作者: Antonio Proto , Carmine Capacchione , Oriana Motta , Francesco De Carlo

DOI: 10.1021/MA034431O

关键词: Ionic polymerizationLiving polymerizationChain transferSolution polymerizationPolymerizationCationic polymerizationCoordination polymerizationChain-growth polymerizationChemistryPolymer chemistry

摘要: Complexes of ZrCl4 incorporating neutral donors such as THF and Et2O activated by methylaluminoxane have been found to be active homogeneous catalytic systems for the polymerization ethylene. Th...

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