Highly soluble Cu(i)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds.
作者： Mehdi Elsayed Moussa , Martin Piesch , Martin Fleischmann , Andrea Schreiner , Michael Seidl
DOI: 10.1039/C8DT03723J
关键词: Chemistry 、 Medicinal chemistry 、 Acetonitrile 、 Salt (chemistry) 、 Phosphorus
摘要: The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAl] = FAl{OC(C6F10)(C6F5)}3) [Cu(CH3CN)4][TEF] (2) ([TEF] Al{OC(CF3)3}4) is presented. Compound 1 reacts with organometallic polyphosphorus complexes [Cp2Mo2(CO)4(η2-P2)] (A) [(Cp*Fe(η5-P5)] (B) salt 2 B to form one new (3) three unprecedented (4–6) phosphorus-rich Cu(I) dimers general formulas [Cu2(μ,η1:η1-A)2(η2-A)2][FAl]2 (3), [Cu2(μ,η1:η1-A)2(η1-CH3CN)4][FAl]2 (4), [Cu2(μ,η1:η1-B)2(η1-CH3CN)4][FAl]2 (5) [Cu2(μ,η1:η1-B)2(η1-CH3CN)4][TEF]2 (6).
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