Synthesis of Optically Active 1-Fluoroalkyl Benzenes.

作者: E. FRITZ-LANGHALS

DOI: 10.1002/CHIN.199431109

关键词: CaesiumOptically activePhotochemistryPolar effectFluorideChemistry

摘要: Abstract A simple synthesis of optically active 1-fluoroalkyl benzenes bearing electron withdrawing substituents is developed. Optically 1-hydroxyalkyl are converted into the methanesulfonates and subsequently 1 by use fluorinating agent cesium fluoride/N-methyl-formamide.

参考文章(1)
Elke Fritz-Langhals, Synthesis of optically active 1-fluoroalkyl benzenes Tetrahedron Letters. ,vol. 35, pp. 1851- 1854 ,(1994) , 10.1016/S0040-4039(00)73178-9