Energetic heterogeneity and molecular size effects in physical adsorption on solid surfaces
作者： A.W Marczewski , A Derylo-Marczewska , M Jaroniec
DOI: 10.1016/0021-9797(86)90309-7
关键词: Thermodynamics 、 Solid surface 、 Adsorption 、 Energy distribution 、 Physical chemistry 、 Langmuir adsorption model 、 Chemistry 、 Molecule 、 Molecular size
摘要: Abstract A simple model of adsorption processes involving simultaneously adsorbent heterogeneity and adsorbate molecule size is presented. The considerations concern from the gas as well liquid phases on solids characterized by different surface topographies. Relationships between energy distribution functions molecular are derived form isotherm equation discussed. theoretical illustrated some calculations.
elsevier.com
sci-hub.se 参考文章(11)
Andrzed Dabrowski, MieczysŁaw Jaroniec, None, Characterization 0f solid-liquid adsorption systems by using Gaussian energy distribution Materials Chemistry and Physics. ,vol. 12, pp. 339- 365 ,(1985) , 10.1016/0254-0584(85)90105-1
M. Jaroniec, A.W. Marczewski, Competitive adsorption of binary gas mixtures on energetically heterogeneous solids Thin Solid Films. ,vol. 92, pp. 385- 392 ,(1982) , 10.1016/0040-6090(82)90164-X
M. Jaroniec, A. Deryło, A.W. Marczewski, An equation for multi-solute adsorption from dilute aqueous solutions involving energetic heterogeneity of the solid and differences in molecular sizes of the solutes Chemical Engineering Science. ,vol. 38, pp. 307- 311 ,(1983) , 10.1016/0009-2509(83)85013-1
Ikuo Abe, Katsumi Hayashi, Mutsuo Kitagawa, Toshihiro Urahata, Adsorptive Mechanism on Activated Carbon in the Liquid Phase. III. The Relationship between the Physical Constants of Organic Compounds and Their Adsorbabilities on Activated Carbon from an Aqueous Solution Bulletin of the Chemical Society of Japan. ,vol. 53, pp. 1199- 1205 ,(1980) , 10.1246/BCSJ.53.1199
S. B. Stocking, Albert E. Waugh, Elements of statistical method Journal of the American Statistical Association. ,vol. 33, pp. 261- ,(1938) , 10.2307/2278944
W Rudziński, L Lajtar, J Zaja̧c, E Wolfram, I Pászli, Ideal adsorption from binary liquid mixtures on heterogeneous solid surfaces: Equations for excess isotherms and heats of immersion Journal of Colloid and Interface Science. ,vol. 96, pp. 339- 359 ,(1983) , 10.1016/0021-9797(83)90038-3
M. Jaroniec, A simple model for the adsorption of mixtures on solids involving energetic heterogeneity of the surface and differences in molecular sizes of the components Thin Solid Films. ,vol. 81, pp. L97- L99 ,(1981) , 10.1016/0040-6090(81)90513-7
M. Jaroniec, A. Dabrowski, G. Nowakowski, H. Herden, W. D. Einicke, R. Sch�llner, Adsorption of 1-olefin/ n -paraffin liquid mixtures on NaX and NaY zeolites Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 3, pp. 85- 93 ,(1985) , 10.1007/BF00658865
D. M. Young, A. D. Crowell, Stuart A. Rice, Physical adsorption of gases Physics Today. ,vol. 16, pp. 80- 82 ,(1963) , 10.1063/1.3050674
D. H. Everett, Thermodynamics of adsorption from solution. Part 2.—Imperfect systems Trans. Faraday Soc.. ,vol. 61, pp. 2478- 2495 ,(None) , 10.1039/TF9656102478