Modeling for pyrolysis of solid particle: kinetics and heat transfer effects
作者： B.V Babu , A.S Chaurasia
DOI: 10.1016/S0196-8904(02)00252-2
关键词: Thermodynamics 、 Finite difference method 、 Prandtl number 、 Heat transfer 、 Reynolds number 、 Chemistry 、 Heat transfer coefficient 、 Kinetic scheme 、 Char 、 Chemical kinetics
摘要: In the present study, a mathematical model to describe the pyrolysis of a single solid particle of biomass is developed by incorporating improvements in the existing model reported in literature. It couples the heat transfer equation with the chemical kinetics equations. The pyrolysis rate has been simulated by a kinetic scheme involving three reactions (primary and secondary): two parallel reactions and a third for the secondary interactions between the volatile and gaseous products and the char. The dependence of convective heat transfer …
elsevier.com
sci-hub.se 参考文章(26)
Kenneth M. Bryden, Kenneth W. Ragland, Christopher J. Rutland, Modeling thermally thick pyrolysis of wood Biomass and Bioenergy. ,vol. 22, pp. 41- 53 ,(2002) , 10.1016/S0961-9534(01)00060-5
C. A. Koufopanos, N. Papayannakos, G. Maschio, A. Lucchesi, Modelling of the pyrolysis of biomass particles. Studies on kinetics, thermal and heat transfer effects Canadian Journal of Chemical Engineering. ,vol. 69, pp. 907- 915 ,(1991) , 10.1002/CJCE.5450690413
K Li, E.M Kennedy, B.Z Dlugogorski, Experimental and computational studies of the pyrolysis of CBrF3, and the reaction of CBrF3 with CH4 Chemical Engineering Science. ,vol. 55, pp. 4067- 4078 ,(2000) , 10.1016/S0009-2509(00)00078-6
Ayhan Demirbaş, Gaseous products from biomass by pyrolysis and gasification: effects of catalyst on hydrogen yield Energy Conversion and Management. ,vol. 43, pp. 897- 909 ,(2002) , 10.1016/S0196-8904(01)00080-2
C. A. Koufopanos, A. Lucchesi, G. Maschio, Kinetic modelling of the pyrolysis of biomass and biomass components Canadian Journal of Chemical Engineering. ,vol. 67, pp. 75- 84 ,(1989) , 10.1002/CJCE.5450670111
V.K. Srivastava, R.K. Jalan, Predictions of concentration in the pyrolysis of biomass materials—I Energy Conversion and Management. ,vol. 35, pp. 1031- 1040 ,(1994) , 10.1016/0196-8904(94)90007-8
Kei Miyanami, Liang-Shih Fan, L. T. Fan, W. P. Walawender, A mathematical model for pyrolysis of a solid particle — effects of the heat of reaction Canadian Journal of Chemical Engineering. ,vol. 55, pp. 317- 325 ,(1977) , 10.1002/CJCE.5450550314
Olivier Boutin, Monique Ferrer, Jacques Lédé, Flash pyrolysis of cellulose pellets submitted to a concentrated radiation: experiments and modelling Chemical Engineering Science. ,vol. 57, pp. 15- 25 ,(2002) , 10.1016/S0009-2509(01)00360-8
D.L. Pyle, C.A. Zaror, Heat transfer and kinetics in the low temperature pyrolysis of solids Chemical Engineering Science. ,vol. 39, pp. 147- 158 ,(1984) , 10.1016/0009-2509(84)80140-2
Lee J. Curtis, Dennis J. Miller, Transport model with radiative heat transfer for rapid cellulose pyrolysis Industrial & Engineering Chemistry Research. ,vol. 27, pp. 1775- 1783 ,(1988) , 10.1021/IE00082A007