Process for preparing functionalized alkyllithium compounds
作者： James Anthony Schwindeman
DOI:
关键词: Bromine 、 Halide 、 Aryl 、 Hydrocarbon 、 Carbon 、 Organic chemistry 、 Polymer chemistry 、 Solvent 、 Chlorine 、 Alkyl 、 Chemistry
摘要: A process for preparing functionalized alkyllithium compounds comprising reacting a fine particle size lithium metal of not more than 300 microns average with an organosiloxyalkyl halide the formula R1R2R3SiORX wherein R?1, R2 and R3? are independently selected from alkyl groups containing 1 to 10 carbon atoms aryl 6 atoms, R is 8 either straight chain or substituted by groups, X chlorine bromine, reaction temperature above 50 °C, medium hydrocarbon solvent conducted in inert atmosphere.
lens.org 参考文章(9)
Robert Charles Morrison, John Francis Engel, Randy Winfred Hall, Conrad William Kamienski, James Anthony Schwindeman, Catalyzed hydrocarbyllithium process ,(1992)
Robert Charles Bening, Carl Lesley Willis, Protected functional initiators for making terminally functionalized polymers ,(1995)
Malcolm John Stewart, Neil Shepherd, Polymerisation of olefinic-containing monomers employing anionic initiators ,(1991)
Eric J. Granger, John F. Engel, James A. Schwindeman, New functionalized initiators for anionic polymerization ,(1995)
Takehiko Fukumoto, Akira Yamamoto, Method for the preparation of an alkynyl compound ,(1990)
Reuben D. Rieke, Preparation and use of (2-butene-1,4-diyl)magnesium complexes in organic synthesis ,(1993)
James A. Schwindeman, Process for preparing trimethylsilyloxy functionalized alkyllithium compounds ,(1995)
James A. Schwindeman, Process for preparing trimethylsilyloxy functionalized alkyllithium ,(1994)
Donald J Peterson, Process for preparing trialkylsilylmethylalkali-metal compounds ,(1967)